无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2003年
7期
745-749
,共5页
李宝龙%李宝宗%徐正%陈久桐
李寶龍%李寶宗%徐正%陳久桐
리보룡%리보종%서정%진구동
晶体结构%三股螺旋%一维链%钴配合物%联吡啶%氢键
晶體結構%三股螺鏇%一維鏈%鈷配閤物%聯吡啶%氫鍵
정체결구%삼고라선%일유련%고배합물%련필정%경건
crystal structure triple helices cobalt complex bipyridine hydrogen bonding
The novel complex { [ Co (bipy) (azpy) 2 (NCS) 2 ] @ H2O } n (where bipy = 4, 4′-bipyridine, azpy = 4, 4′-azobisp-yridine) has been synthesized and characterized by elemental analyses, IR, UV, thermal analyses, and vari-able-temperature magnetic susceptibility. The crystal (C32H26CoN12OS2, Mr = 717.70) belongs to the orthorhombic,space group Pnna, a =2. 21312(16)nm, b = 1.40403(10)nm, c = 1. 14237(8)nm, V=3. 5497(4)nm3, Z =4,Dc = 1. 343g @ cm-3, μ=0. 645mm-1, F(000) = 1476, and final R1 =0. 0691, wR2 =0. 1129 for 231 parametersand 1674 observed reflections [ I > 2.00 σ(I) ]. The Co (Ⅱ) atom is, in a distorted octahedral geometry, coordi-nated by six nitrogen atoms from two bridging bipy, two monodentate azpy, and two thiocyanate groups. Thebridging ligand bipy links Co (Ⅱ) atoms to form the infinite "rod" with terminal coordination azpy ligand acting assidearms. Unprecedented three parallel interpenetrating two-dimensional (4, 4) networks and novel infinite triplehelices are formed via hydrogen-bonding interactions. CCDC: 155588.