化学改性二氧化锰结构表征
화학개성이양화맹결구표정
Preparation, Structure and Properties of Chemical Modified MnO2
  • 万方数据
    中国科学技术大学学报 중국과학기술대학학보
    JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA
    2001年 3期 334-338 ,共5页

    夏定国%刘涛%汪夏燕%焦庆影%杨辉

    하정국%류도%왕하연%초경영%양휘

    改性二氧化锰%XPS%EXAFS 改性二氧化錳%XPS%EXAFS
    개성이양화맹%XPS%EXAFS
    应用扩展X射线精细结构（EXAFS）技术及光电子能谱研究改性MnO2的结构.结果表明：掺杂原子进入了MnO2晶格中，锰的第一壳层配位数下降，并且增大高壳层配位原子的无序度.
    응용확전X사선정세결구（EXAFS）기술급광전자능보연구개성MnO2적결구.결과표명：참잡원자진입료MnO2정격중，맹적제일각층배위수하강，병차증대고각층배위원자적무서도.
    Modified MnO2 was prepared by solid phase reaction. The sampleshowed good electrochemical properties. The structural aspects were studied with extended X-ray absorption fine structure and XPS. The results indicate that doped Bi and Pb enter the lattice of MnO2 rather than a physical mixture. The coordination number of the first shell of the Mn atom decreases. The EXAFS resules show that the disorder of Mn atoms in modified MnO2 largely increases in higher shell compared with that of non-modified MnO2.
    원문보기 원문다운로드 사이트로이동
저자의 최근 논문