二甲基·[4-硝基-2-(氮杂苯并-15-冠-5)-1-酚氧基]合镓(Ⅲ)配合物的晶体结构
이갑기·[4-초기-2-(담잡분병-15-관-5)-1-분양기]합가(Ⅲ)배합물적정체결구
Crystal Structure of Complex Dimethylgallium-[4-nitro-2-(N-benzo-15-crown-5)-1-phenoxide]
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2001年 3期 431-434 ,共4页

    毕武%张进琪%沈曦%田敬智%邹惠仙

    필무%장진기%침희%전경지%추혜선

    三甲基镓氮杂冠醚晶体结构 三甲基鎵氮雜冠醚晶體結構
    삼갑기가담잡관미정체결구


    The complex dimethylgallium-[4-nitro-2-(N-benzo- 15-crown-5)-1-phenoxi de] (C23 H31 N2O7Ga)has been synthesized by the method reported. The crystal X-ray diffraction analysis shows that the crystal belongs to the triclinic with space group P1, M = 517.23 and the unit cell parameters: a=1.4501 (2), b=1.5090(2),c=1.3865(6)nm, α=105.58(1),β= 117.26(2), γ=66.812(8)°,V=2.464546nm3, Z=4, Dc=1.39g·cm-3, μ=11.6cm-1, F(000)=1080, R=0.051,Rw=0.064. The coordination number of Ga is four and the gallium atom is located in a distorted tetrahedron structure.
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