化学研究
化學研究
화학연구
CHEMICAL RESEARCHES
2001年
1期
49-51
,共3页
潘卉%赵纪冬%关会立%李润明%高青雨
潘卉%趙紀鼕%關會立%李潤明%高青雨
반훼%조기동%관회립%리윤명%고청우
3-丙烯酰胺基-9-乙基咔唑%二苯基碘鎓盐%甲基丙烯酸甲酯%光聚合
3-丙烯酰胺基-9-乙基咔唑%二苯基碘鎓鹽%甲基丙烯痠甲酯%光聚閤
3-병희선알기-9-을기잡서%이분기전옹염%갑기병희산갑지%광취합
研究了3-丙烯酰胺基-9-乙基咔唑(AAECZ)/氯化二苯基碘鎓盐(DPIOC)组成的光敏引发体系引发的甲基丙烯酸甲酯(MMA)光聚合,并研究了各因素对聚合速率的影响,得到了聚合动力学方程;讨论了温度对聚合反应的影响,并探讨了引发机理.
研究瞭3-丙烯酰胺基-9-乙基咔唑(AAECZ)/氯化二苯基碘鎓鹽(DPIOC)組成的光敏引髮體繫引髮的甲基丙烯痠甲酯(MMA)光聚閤,併研究瞭各因素對聚閤速率的影響,得到瞭聚閤動力學方程;討論瞭溫度對聚閤反應的影響,併探討瞭引髮機理.
연구료3-병희선알기-9-을기잡서(AAECZ)/록화이분기전옹염(DPIOC)조성적광민인발체계인발적갑기병희산갑지(MMA)광취합,병연구료각인소대취합속솔적영향,득도료취합동역학방정;토론료온도대취합반응적영향,병탐토료인발궤리.
In this paper, the photopolymrization of methyl methacrylate initiated by 3-acrylamide-9-ethylcarbazole (AAECZ) and diphenyliodonium chloride salt was studied, the photopolymerization rate equation and its activation energies were obtained. The mechanism of initiation was discussed.