CAJ | 학술논문

合成了RB-Zn配合物，晶体结构分析结果表明配合物组成为晶体属单斜晶系、空间群为P21/n(#14)，晶胞参数为a研究了配合物的物质的量电导、IR和荧光光谱，同时对配体配合物的半导体行为进行了考察．
합성료RB-Zn배합물，정체결구분석결과표명배합물조성위정체속단사정계、공간군위P21/n(#14)，정포삼수위a연구료배합물적물질적량전도、IR화형광광보，동시대배체배합물적반도체행위진행료고찰．
The preparation and characterization of Zn(Ⅱ) complex with RB (Rhodamine Bwith dehydrogen－chloride), [Zn(RB) (OAc)2 (H2O)] (A) , is described. Crystal of A ismonoclinic, P21/n with a =1.029 8(2) nm, b=1.890 1(4) nm, c=1.666 0(6) nm andβ= 105.24(3)° and have four formula units in the unit cell. The structure was determinedby standard methods and refined to R =0. 060, Rw=0. 068 on the basis of 5 755 independent reflections. The resultsuggests that coordination bond formed between the Zn atom andRB through the carboxylate group of the dye. The electrical conductivity of the complex andother related materials were also investigated.