CAJ | 학술논문

采用稀硫酸浸湿样品，正己烷提取，乙酸酐衍生后以毛细管气相色谱分离测定的方法对纺织品中五氯酚、三氯酚残留量进行了同时测定，探讨了提取、净化及色谱分析条件。方法回收率范围:三氯酚84.8％～98.1％,五氯酚88.0％～100.2％。相对标准偏差:三氯酚1.54％～2.33％,五氯酚3.48％。方法的检出限（质量分数）分别为2，4，6-三氯酚：1.0×10－9,2，4，5-三氯酚：5.0×10,五氯酚:2.0×10－9。
채용희류산침습양품，정기완제취，을산항연생후이모세관기상색보분리측정적방법대방직품중오록분、삼록분잔류량진행료동시측정，탐토료제취、정화급색보분석조건。방법회수솔범위:삼록분84.8％～98.1％,오록분88.0％～100.2％。상대표준편차:삼록분1.54％～2.33％,오록분3.48％。방법적검출한（질량분수）분별위2，4，6-삼록분：1.0×10－9,2，4，5-삼록분：5.0×10,오록분:2.0×10－9。
A method for the simultaneous separation and determination oftrichlorophenols and pentachlorophenol residues in textiles is reported. Samples were soaked in dilute sulphuric acid solution, and trichlorophenols and pentachlorophenol were extracted with n-hexane, acetylated with acetic anhydride and analyzed by capillary gas chromatography with ECD. The extraction, purification and chromatographic separation conditions have been investigated. The recoveries of the method were evaluated by spiked chlorophenols studied at concentration levels of 25～100 ng/g. The recoveries were 84.8%~98.1% and 88.0%～100.2% for trichlorophenols and pentachlorophenol, respectively, RSD were 1.54%～2.33% and 3.48% , respectively. The detection limits were 1.0 ng/g for 2,4,6-trichlorophenol, 5.0 ng/g for 2,4,6-trichlorophenol and 2.0 ng/g for pentachlorophenol.