精细与专用化学品
精細與專用化學品
정세여전용화학품
FINE AND SPECIALTY CHEMICALS
2011年
11期
27-31
,共5页
纤维素%聚乳酸%共混%结晶结构%降解性
纖維素%聚乳痠%共混%結晶結構%降解性
섬유소%취유산%공혼%결정결구%강해성
cellulose%polylactic acid%blending%crystal structure%degradation
将微晶纤维素溶于离子液体中,加入不同质量的聚乳酸,配制成共混溶液并成膜。通过红外光谱对其结构进行测定,证明共混物制备成功。X-衍射、SEM及DSC测试结果表明,共混物之间具有较好的相容性,当微晶纤维素与聚乳酸的质量比为60:40时共混效果较好,较易成膜,且二者的结晶过程得到互相促进,结晶完美度及晶体尺寸提高。同时,DSC测试结果表明,不同质量比的纤维素-聚乳酸共混物具有不同的结晶度,且纤维素与聚乳酸的质量比为60:40时亦具有较好的化学及生物降解性。
將微晶纖維素溶于離子液體中,加入不同質量的聚乳痠,配製成共混溶液併成膜。通過紅外光譜對其結構進行測定,證明共混物製備成功。X-衍射、SEM及DSC測試結果錶明,共混物之間具有較好的相容性,噹微晶纖維素與聚乳痠的質量比為60:40時共混效果較好,較易成膜,且二者的結晶過程得到互相促進,結晶完美度及晶體呎吋提高。同時,DSC測試結果錶明,不同質量比的纖維素-聚乳痠共混物具有不同的結晶度,且纖維素與聚乳痠的質量比為60:40時亦具有較好的化學及生物降解性。
장미정섬유소용우리자액체중,가입불동질량적취유산,배제성공혼용액병성막。통과홍외광보대기결구진행측정,증명공혼물제비성공。X-연사、SEM급DSC측시결과표명,공혼물지간구유교호적상용성,당미정섬유소여취유산적질량비위60:40시공혼효과교호,교역성막,차이자적결정과정득도호상촉진,결정완미도급정체척촌제고。동시,DSC측시결과표명,불동질량비적섬유소-취유산공혼물구유불동적결정도,차섬유소여취유산적질량비위60:40시역구유교호적화학급생물강해성。
The cellulose-polylactie acid blending membrane was prepared via mixed solvent method.Firstly, microcrystalline cellulose was dissolved in ionic liquid,and then a different quality of polylactic acid was added. Infrared spectroscopy(FTIR) determined that blending membrane was prepared successfully.According to the results of X-ray diffraction,SEM and DSC,the microcrystalline cellulose and polylactic acid showed good compatibility with each other.When the mass ratio of microcrystalline cellulose to polylactic acid was 60:40,the membrane was easily obtained.At the same time,the crystallization process was promoted,and crystallization degree and crystal size were also increased.The results of DSC also showed that different mass ratio of cellulosepolylactic acid membrane had different degree of crystallinity.When the mass ratio of microcrystalline cellulose to polylactic acid was 60:40,the membrane also had good chemical and biological degradation.