化学与生物工程
化學與生物工程
화학여생물공정
CHEMISTRY & BIOENGINEERING
2009年
7期
19-21,28
,共4页
唐俊峰%李群丽%刘红涛%陈连清%孙杰%吕康乐%邓克俭
唐俊峰%李群麗%劉紅濤%陳連清%孫傑%呂康樂%鄧剋儉
당준봉%리군려%류홍도%진련청%손걸%려강악%산극검
四溴丙基四(1,4-二噻(口英))四氮杂卟啉锌%合成与表征%活化分子氧%光催化降解
四溴丙基四(1,4-二噻(口英))四氮雜卟啉鋅%閤成與錶徵%活化分子氧%光催化降解
사추병기사(1,4-이새(구영))사담잡계람자%합성여표정%활화분자양%광최화강해
zinc(Ⅱ) tetra(1,4-dithiin)porphyrazine bearing peripheral tetrapropyl-bromine%synthesis and characterization%activate molecular oxygen%photocatalytic degradation
以镁离子为模板,2,3-二氰基-5-溴丙基-1,4-二噻(口英)为前驱体,成功地合成了四溴丙基四(1,4-二噻(口英))四氮杂卟啉锌,用紫外光谱、红外光谱、元素分析和X-射线光电子能谱对其进行了表征,并将目标化合物负载到树脂上,初步考察了其对苯酚的光催化降解效果.
以鎂離子為模闆,2,3-二氰基-5-溴丙基-1,4-二噻(口英)為前驅體,成功地閤成瞭四溴丙基四(1,4-二噻(口英))四氮雜卟啉鋅,用紫外光譜、紅外光譜、元素分析和X-射線光電子能譜對其進行瞭錶徵,併將目標化閤物負載到樹脂上,初步攷察瞭其對苯酚的光催化降解效果.
이미리자위모판,2,3-이청기-5-추병기-1,4-이새(구영)위전구체,성공지합성료사추병기사(1,4-이새(구영))사담잡계람자,용자외광보、홍외광보、원소분석화X-사선광전자능보대기진행료표정,병장목표화합물부재도수지상,초보고찰료기대분분적광최화강해효과.
The zinc(Ⅱ) tetra(1,4-dithiin)porphyrazine bearing peripheral tetrapropyl-bromine has been synthesized according to the template reaction method from prepared intermediate of 2,3-dicyano-5-propyl-bromine-1, 4-dithiin in n-butyl alcohol.It is characterized by UV-Vis, FTIR, 1HNMR, XPS and elemental analysis. Furthermore, the aim compound is loaded on the resin and the photocatalytic properties on phenol are investigated.
