中国表面工程
中國錶麵工程
중국표면공정
CHINA SURFACE ENGINEERING
2010年
2期
30-35,41
,共7页
陈家才%王旭东%孙冬柏%孟惠民%俞宏英%张连飞
陳傢纔%王旭東%孫鼕柏%孟惠民%俞宏英%張連飛
진가재%왕욱동%손동백%맹혜민%유굉영%장련비
热喷涂%Zn涂层%浪花飞溅区%灰关联分析
熱噴塗%Zn塗層%浪花飛濺區%灰關聯分析
열분도%Zn도층%랑화비천구%회관련분석
thermal spraying%Zn coating%splash zone%grey relational grade analysis
海盐粒子浓度大、干湿交替频繁、海水冲击是浪花飞溅区腐蚀的3个关键性因素.文中以热喷Zn涂层为研究对象,设计了4种循环腐蚀试验制度:①盐雾-驻留循环;②盐雾-驻留-飞溅循环;③盐雾-干燥循环;④盐雾-干燥-飞溅循环,采用失重测量和电化学测量分别研究了涂层在这4种模拟环境下的腐蚀行为及规律,并应用加速转换因子法及灰关联分析对各循环腐蚀试验制度下的加速性、模拟性进行了研究,并为此设计了一个飞溅模拟研究装置以实现浪花飞溅冲击的模拟.试验结果表明:盐雾+驻留循环造成涂层的腐蚀最严重;盐雾+驻留+飞溅循环则能较好的模拟浪花飞溅区的腐蚀情况,可实现室内的热喷Zn涂层在浪花飞溅区腐蚀的模拟.
海鹽粒子濃度大、榦濕交替頻繁、海水遲擊是浪花飛濺區腐蝕的3箇關鍵性因素.文中以熱噴Zn塗層為研究對象,設計瞭4種循環腐蝕試驗製度:①鹽霧-駐留循環;②鹽霧-駐留-飛濺循環;③鹽霧-榦燥循環;④鹽霧-榦燥-飛濺循環,採用失重測量和電化學測量分彆研究瞭塗層在這4種模擬環境下的腐蝕行為及規律,併應用加速轉換因子法及灰關聯分析對各循環腐蝕試驗製度下的加速性、模擬性進行瞭研究,併為此設計瞭一箇飛濺模擬研究裝置以實現浪花飛濺遲擊的模擬.試驗結果錶明:鹽霧+駐留循環造成塗層的腐蝕最嚴重;鹽霧+駐留+飛濺循環則能較好的模擬浪花飛濺區的腐蝕情況,可實現室內的熱噴Zn塗層在浪花飛濺區腐蝕的模擬.
해염입자농도대、간습교체빈번、해수충격시랑화비천구부식적3개관건성인소.문중이열분Zn도층위연구대상,설계료4충순배부식시험제도:①염무-주류순배;②염무-주류-비천순배;③염무-간조순배;④염무-간조-비천순배,채용실중측량화전화학측량분별연구료도층재저4충모의배경하적부식행위급규률,병응용가속전환인자법급회관련분석대각순배부식시험제도하적가속성、모의성진행료연구,병위차설계료일개비천모의연구장치이실현랑화비천충격적모의.시험결과표명:염무+주류순배조성도층적부식최엄중;염무+주류+비천순배칙능교호적모의랑화비천구적부식정황,가실현실내적열분Zn도층재랑화비천구부식적모의.
Thermal spraying Zn coating for marine environment, especially in splash zone, are degraded due to different type of weathering parameters, mainly high salt particle concentration, frequently dry/wet and seawater splash three key factors. In this experimentation, the corrosion behavior of thermal spraying Zn coating in the simulate corrosion environment of splash zone have been studied by 4 different cyclic corrosion test systems: salt spray-dwell, salt spray-dwell - splash, salt spray-dry and salt spray-dry -splash cycle test. Acceleration and simulation of thermal spraying Zn coating in 4 cyclic corrosion test systems by Acceleration Shift Factor and grey relational space analysis were investigation. The experiment results show that the methods are effective and feasible. The salt spray-dwell-splash cycle test was one of a good method to simulate corrosion environment of splash zone in accordance with grey relational grade and experiment results. Meanwhile, a splash simulation test unit have been designed and made.