安徽大学学报（自然科学版）
安徽大學學報（自然科學版）
안휘대학학보（자연과학판）
JOURNAL OF ANHUI UNIVERSITY(NATURAL SCIENCES EDITION)
2009年
6期
52-55
,共4页
ZnO纳米晶%拉曼光谱%尺寸效应
ZnO納米晶%拉曼光譜%呎吋效應
ZnO납미정%랍만광보%척촌효응
ZnO nanocrystal%Raman spectrum%size effect
通过溶胶-凝胶法制备了5～31 nm氧化锌纳米晶,测量了它们的拉曼光谱,结果表明二级拉曼模随粒径减小相对强度增大,归因于尺寸效应.新出现的938 cm~(-1)模指认为来自表面氧空位.
通過溶膠-凝膠法製備瞭5～31 nm氧化鋅納米晶,測量瞭它們的拉曼光譜,結果錶明二級拉曼模隨粒徑減小相對彊度增大,歸因于呎吋效應.新齣現的938 cm~(-1)模指認為來自錶麵氧空位.
통과용효-응효법제비료5～31 nm양화자납미정,측량료타문적랍만광보,결과표명이급랍만모수립경감소상대강도증대,귀인우척촌효응.신출현적938 cm~(-1)모지인위래자표면양공위.
Through the method of Sol-Gel, we prepared the ZnO nanocrystals in size of 5-31 nm, and then their Raman spectra were measured. Results showed that the intensity of two-order Raman scattering was increased while the grain size decreased, due to size effect. New 938 cm~(-1) mode was assigned to oxide vacancies on surface of nanocrystal.
