膜科学与技术
膜科學與技術
막과학여기술
MEMBRANE SCIENCE AND TECHNOLOGY
2010年
1期
96-99
,共4页
齐笑飞%乔建援%毕生雷%张一飞%孙沛勇
齊笑飛%喬建援%畢生雷%張一飛%孫沛勇
제소비%교건원%필생뢰%장일비%손패용
金属膜%1,3-丙二醇发酵液%膜清洗
金屬膜%1,3-丙二醇髮酵液%膜清洗
금속막%1,3-병이순발효액%막청세
metal membranes%1,3- propanediol fermentation broth%membrane cleaning
考察了1,3-丙二醇发酵液金属膜过滤在不同浓缩比下的拟稳定通量、黏度及湿固含量变化,在此基础上初步探讨了膜的污染机理,提出了有效的膜清洗方法.结果表明:50 nm的膜适用于1,3-丙二醇发酵液的膜过滤,按料液体积35%,加入去离子水、浓缩倍率在9左右时回收率达到95%.膜污染的主要来源是蛋白,有效的化学清洗方法是:用质量分数为1%NaOH和0.05%EDTA混合溶液清洗膜30 min后,再以0.5%HNO_3溶液清洗5 min,膜通量可迅速恢复.
攷察瞭1,3-丙二醇髮酵液金屬膜過濾在不同濃縮比下的擬穩定通量、黏度及濕固含量變化,在此基礎上初步探討瞭膜的汙染機理,提齣瞭有效的膜清洗方法.結果錶明:50 nm的膜適用于1,3-丙二醇髮酵液的膜過濾,按料液體積35%,加入去離子水、濃縮倍率在9左右時迴收率達到95%.膜汙染的主要來源是蛋白,有效的化學清洗方法是:用質量分數為1%NaOH和0.05%EDTA混閤溶液清洗膜30 min後,再以0.5%HNO_3溶液清洗5 min,膜通量可迅速恢複.
고찰료1,3-병이순발효액금속막과려재불동농축비하적의은정통량、점도급습고함량변화,재차기출상초보탐토료막적오염궤리,제출료유효적막청세방법.결과표명:50 nm적막괄용우1,3-병이순발효액적막과려,안료액체적35%,가입거리자수、농축배솔재9좌우시회수솔체도95%.막오염적주요래원시단백,유효적화학청세방법시:용질량분수위1%NaOH화0.05%EDTA혼합용액청세막30 min후,재이0.5%HNO_3용액청세5 min,막통량가신속회복.
At the different concentration rate the change of quasi -steady filtrate flux, viscosity and wet solid content for 1,3- propanediol fermentation broth were investigated by metal membranes.On the basis of this, the mechanism of membrane fouling was pre- investigated and the method of membrane cleaning was obtained.It showed that 50 nm membrane was suited for membrane filtration of 1,3-propanediol fermentation broth.The recovery rate could be improved to 95 % by adding 35 % of the dieonized water, the concentration ratio of about 9.The major source of membrane pollution was protein and effective chemical method of cleaning was that it took 40 minutes to clean membranes by mixed solution composed of 1% NaOH and 0.05 % EDTA, where-after, 0.5 % HNO_3 was used to clean membrane for 5 minutes.The results indicated that membrane flux could be recovered rapidly.