半导体学报
半導體學報
반도체학보
CHINESE JOURNAL OF SEMICONDUCTORS
2006年
8期
1360-1366
,共7页
陈金伙%王永顺%朱海华%胡加兴%张福甲
陳金夥%王永順%硃海華%鬍加興%張福甲
진금화%왕영순%주해화%호가흥%장복갑
CuPc/SiO2%X射线光电子能谱%表面界面分析
CuPc/SiO2%X射線光電子能譜%錶麵界麵分析
CuPc/SiO2%X사선광전자능보%표면계면분석
CuPc/SiO2%X-ray photoelectron spectroscopy%surface and interface analysis
利用热生长工艺和热蒸发方法分别获得CuPc和SiO2薄膜层,通过原子力显微镜和X射线光电子能谱对其表面界面电子状态进行了研究,并采用高斯拟合方法对各谱进行了详细分析.结果表明,在氧原子的作用下,N1s,C1s,O1s 和Cu2p都经受了一定的化学位移,从而使得各原子间的相互作用强度有所改变,这是导致OFET性能劣化的重要原因之一.对OFET而言,采用溅射工艺制备的SiO2层应比热氧化生长的SiO2层更合适.
利用熱生長工藝和熱蒸髮方法分彆穫得CuPc和SiO2薄膜層,通過原子力顯微鏡和X射線光電子能譜對其錶麵界麵電子狀態進行瞭研究,併採用高斯擬閤方法對各譜進行瞭詳細分析.結果錶明,在氧原子的作用下,N1s,C1s,O1s 和Cu2p都經受瞭一定的化學位移,從而使得各原子間的相互作用彊度有所改變,這是導緻OFET性能劣化的重要原因之一.對OFET而言,採用濺射工藝製備的SiO2層應比熱氧化生長的SiO2層更閤適.
이용열생장공예화열증발방법분별획득CuPc화SiO2박막층,통과원자력현미경화X사선광전자능보대기표면계면전자상태진행료연구,병채용고사의합방법대각보진행료상세분석.결과표명,재양원자적작용하,N1s,C1s,O1s 화Cu2p도경수료일정적화학위이,종이사득각원자간적상호작용강도유소개변,저시도치OFET성능열화적중요원인지일.대OFET이언,채용천사공예제비적SiO2층응비열양화생장적SiO2층경합괄.
A CuPc/SiO2 sample is fabricated.Its morphology is characterized by atomic force microscopy,and the electron states are investigated by X-ray photoelectron spectroscopy.In order to investigate these spectra in detail,all of these spectra are normalized to the height of the most intense peak,and each component is fitted with a single Gaussian function.Analysis shows that the O element has great bearing on the electron states and that SiO2 layers produced by spurting technology are better than those produced by oxidation technology.