CAJ | 학술논문

采用改进的次氯酸盐氧化法合成了高铁酸钾氧化剂,并对其进行了表征.提出了以高铁酸钾为氧化剂的高效,清洁氧化生产超低硫戊烷新方法,考察了氧化反应条件对脱硫效果的影响,并给出了氧化脱硫反应机理.在戊烷20 mL、K_2FeO_40.1786 g、催化剂ZSW-1 0.5 mL条件下,30℃下氧化60 min后,反应产物采用5%的NaOH萃取,戊烷中硫含量由50 mg/L降到0.632 mg/L,脱硫率为98.7%.
채용개진적차록산염양화법합성료고철산갑양화제,병대기진행료표정.제출료이고철산갑위양화제적고효,청길양화생산초저류무완신방법,고찰료양화반응조건대탈류효과적영향,병급출료양화탈류반응궤리.재무완20 mL、K_2FeO_40.1786 g、최화제ZSW-1 0.5 mL조건하,30℃하양화60 min후,반응산물채용5%적NaOH췌취,무완중류함량유50 mg/L강도0.632 mg/L,탈류솔위98.7%.
Potassium ferrate is prepared by an improved hypochlorite oxidation method and then characterized. A new, effective and green approach for ultralow-sulfur pentane production is proposed using potassium ferrate as oxidant. Effects of oxidation conditions on the desulphurization and the oxidation mechanism are discussed. With 0.1786 g of K_2FeO_4. 0.5 mL of ZSW-1 catalyst, 20 mL of pentane under 30℃ for 60 min, the reaction mixture was extracted with 5%NaOH aqueous solution, the sulphur content was reduced from 50 mg/L to 0.632 mg/L, and the desulfurization ratio reached to 98.7 %.