农药学学报
農藥學學報
농약학학보
CHINESE JOURNAL OF PESTICIDE SCIENCE
2010年
1期
73-78
,共6页
吕金红%李建法%王杰%薛琴%吴丽琴
呂金紅%李建法%王傑%薛琴%吳麗琴
려금홍%리건법%왕걸%설금%오려금
除草剂%2,4-D%粘土%吸附%控制释放
除草劑%2,4-D%粘土%吸附%控製釋放
제초제%2,4-D%점토%흡부%공제석방
herbicide%2,4-D%clay%adsorption%controlled release
采用无机/有机复合改性粘土作制剂载体,探讨了其对阴离子型除草剂2,4-D的控制释放作用,目的在于延长2,4-D的持效期,同时减轻其污染.利用无机和有机改性的结合优势,复合改性粘土具有更强的吸附性能,能够显著延缓2,4-D在水中和土壤中的释放.分析其水中释放动力学数据得出,2,4-D释放50%所需时间(t_(50))长达73.8 h,远大于有机改性粘土作载体时的1 h.土壤层释放实验表明,当2,4-D载药量在20~80 mg/g之间时,复合改性粘土均能保持良好的控制释放效果.
採用無機/有機複閤改性粘土作製劑載體,探討瞭其對陰離子型除草劑2,4-D的控製釋放作用,目的在于延長2,4-D的持效期,同時減輕其汙染.利用無機和有機改性的結閤優勢,複閤改性粘土具有更彊的吸附性能,能夠顯著延緩2,4-D在水中和土壤中的釋放.分析其水中釋放動力學數據得齣,2,4-D釋放50%所需時間(t_(50))長達73.8 h,遠大于有機改性粘土作載體時的1 h.土壤層釋放實驗錶明,噹2,4-D載藥量在20~80 mg/g之間時,複閤改性粘土均能保持良好的控製釋放效果.
채용무궤/유궤복합개성점토작제제재체,탐토료기대음리자형제초제2,4-D적공제석방작용,목적재우연장2,4-D적지효기,동시감경기오염.이용무궤화유궤개성적결합우세,복합개성점토구유경강적흡부성능,능구현저연완2,4-D재수중화토양중적석방.분석기수중석방동역학수거득출,2,4-D석방50%소수시간(t_(50))장체73.8 h,원대우유궤개성점토작재체시적1 h.토양층석방실험표명,당2,4-D재약량재20~80 mg/g지간시,복합개성점토균능보지량호적공제석방효과.
Clay complexly modified with inorganic and organic cations was used as the carrier of anionic herbicide 2,4-D, and its performance on controlling the herbicide' s release was investigated. The aim of this research was to prolong the activity of 2,4-D, and reduce its pollution. The modified clay had much higher adsorbability, and could obviously slow the release of 2,4-D in both water and soil. The results of release kinetics in water indicated the time taken for 50% 2,4-D to be released was as long as 73.8 h, and much longer than that of organically modified clay (1 h) being used as the carrier. According to the release experiments in soil layer, the complexly modified clay has very good performance on controlling 2,4-D release when the loading amount ranged between 20~80 mg/g.