无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2005年
11期
1710-1714
,共5页
韩建林%杨宝海%颜黎均%沈应中%潘毅
韓建林%楊寶海%顏黎均%瀋應中%潘毅
한건림%양보해%안려균%침응중%반의
羧酸银配合物%膦%CVD%TG
羧痠銀配閤物%膦%CVD%TG
최산은배합물%련%CVD%TG
silver%carboxylates%phosphine%CVD%TG
A new series of diphenyl(2-methoxyphenyl)phosphine coordinated silver carboxylates [Ag(O2CR)(L): L=Diphenyl(2-methoxyphenyl)phosphine, R=CH3 (3a), CH3CH2 (3b),i-Pr (3c), EtOCH2 (3d), p-CH3OPh (3e), CH3CH= CH (3f), (CH3)2C=CH (3g), ClCH2 (3h)] were synthesized by reaction of diphenyl(2-methoxyphenyl)phosphine with the related silver carboxylates in chloroform. The complexes were obtained as white solids in high yields and their structures have been characterized by elemental analysis, 1H NMR, 13C NMR, 31P NMR, IR spectroscopy. The thermal stability of these complexes has been studied by the TG analysis. These complexes can be used in the growth of metal thin films via aerosol-assisted chemical vapor deposition (AACVD) techniques.
