CAJ | 학술논문

合成了一种新的三桥连双铁(Ⅲ)配合物[Fe2(IDB)2(O)(CH3CO2)2]Cl2·CH3OH,IDB为N,N'-di(2'-benzimidazolyl methyl) imine,利用单晶x射线衍射及其它谱学方法对所合成配合物进行了表征.每个双核单元的两个铁原子均通过一个氧原子和两个醋酸根连接,每个铁原子同时还与位于桥氧原子对位的三齿配体IDB重脂肪链上氮原子相结合,每个铁(Ⅲ)中心为一变形八面体结构.对该新化合物的拉曼光谱进行了研究并对一些谱峰进行了归属.
합성료일충신적삼교련쌍철(Ⅲ)배합물[Fe2(IDB)2(O)(CH3CO2)2]Cl2·CH3OH,IDB위N,N'-di(2'-benzimidazolyl methyl) imine,이용단정x사선연사급기타보학방법대소합성배합물진행료표정.매개쌍핵단원적량개철원자균통과일개양원자화량개작산근련접,매개철원자동시환여위우교양원자대위적삼치배체IDB중지방련상담원자상결합,매개철(Ⅲ)중심위일변형팔면체결구.대해신화합물적랍만광보진행료연구병대일사보봉진행료귀속.
A triply bridged dirron ( Ⅲ ) complex [Fe2(IDB)2(O) (CH3CO2)2]Cl2CH3OH, in which IDB is N, N' -di(2' -benzimidazolyl methyl) imine, has been synthesized and characterized by single - crystal X - ray diffractometry and spectrometry. Both iron( Ⅲ ) atoms of the binuclear unit are bridged by one oxy atom and two acetate groups. Each iron atom is also bound to facially - coordinating tridentate IDB ligand with the aliphatic nitrogen donor situated trans to theμ- oxy atom. Each iron ( m ) centers is in a distorted octahedral symmetry. The Raman spectroscopy of the novel complexes have been studied and some peak have been attributed.