石油化工应用
石油化工應用
석유화공응용
PETROCHEMICAL INDUSTRY APPLICATION
2012年
1期
69-71
,共3页
冯质壮%刘琴%董海玲%王纪元
馮質壯%劉琴%董海玲%王紀元
풍질장%류금%동해령%왕기원
空心球%二氧化硅%分散聚合%模板
空心毬%二氧化硅%分散聚閤%模闆
공심구%이양화규%분산취합%모판
hollow spheres%silica%dispersion polymerization%template
在乙醇/水的混合溶液中,采用聚乙烯吡咯烷酮(PVP)为分散剂,偶氮二异丁腈(AIBN)为引发剂,通过分散聚合法制备出聚苯乙烯(PS)微球,然后以微球为模板,将产生的PS粒子作为核,SiO_2作为壳。SiO_2空心球通过在600℃时的热分解可得到。对制得的空心球通过热分析仪、扫描电子显微镜进行表征。对图进行分析,并讨论影响因素。
在乙醇/水的混閤溶液中,採用聚乙烯吡咯烷酮(PVP)為分散劑,偶氮二異丁腈(AIBN)為引髮劑,通過分散聚閤法製備齣聚苯乙烯(PS)微毬,然後以微毬為模闆,將產生的PS粒子作為覈,SiO_2作為殼。SiO_2空心毬通過在600℃時的熱分解可得到。對製得的空心毬通過熱分析儀、掃描電子顯微鏡進行錶徵。對圖進行分析,併討論影響因素。
재을순/수적혼합용액중,채용취을희필각완동(PVP)위분산제,우담이이정정(AIBN)위인발제,통과분산취합법제비출취분을희(PS)미구,연후이미구위모판,장산생적PS입자작위핵,SiO_2작위각。SiO_2공심구통과재600℃시적열분해가득도。대제득적공심구통과열분석의、소묘전자현미경진행표정。대도진행분석,병토론영향인소。
PVP as the stabilizer and AIBN as the initiator PS spheres were prepared in ethanol/water medium by dispersion polymerization method.Silica spheres which were composited with PS as a core and silica as the shell were prepared by using polystyrene(PS)as a templete.Hollow silica spheres are obtained in a following step by thermal degradation of the PS cores at 600 temperature.Thermogravimetric analysis and SEM were used to characterize the monodispersed hollow silica.Factors of influence were put forward and charts were analyzed.