广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
3期
7-9,39
,共4页
孙哲%全凤玉%徐文%朱立华%李海宁%夏延致
孫哲%全鳳玉%徐文%硃立華%李海寧%夏延緻
손철%전봉옥%서문%주립화%리해저%하연치
海藻酸纤维%臧红T%吸附%动力学
海藻痠纖維%臧紅T%吸附%動力學
해조산섬유%장홍T%흡부%동역학
alginic acid fibre%Safranine T%adsorption%kinetics
以自制海藻酸纤维为吸附剂,研究它对臧红T的吸附性能。用准一级动力学方程、指数函数方程、准二级动力学方程、粒子扩散方程、Elovich方程和双常数方程对不同染料浓度、吸附时间的曲线进行拟合。结果表明,后四种方程的拟合度较好,这说明此吸附是复杂的非均相扩散吸附过程,存在化学吸附,且膜扩散和颗粒内扩散共同控制吸附速率。
以自製海藻痠纖維為吸附劑,研究它對臧紅T的吸附性能。用準一級動力學方程、指數函數方程、準二級動力學方程、粒子擴散方程、Elovich方程和雙常數方程對不同染料濃度、吸附時間的麯線進行擬閤。結果錶明,後四種方程的擬閤度較好,這說明此吸附是複雜的非均相擴散吸附過程,存在化學吸附,且膜擴散和顆粒內擴散共同控製吸附速率。
이자제해조산섬유위흡부제,연구타대장홍T적흡부성능。용준일급동역학방정、지수함수방정、준이급동역학방정、입자확산방정、Elovich방정화쌍상수방정대불동염료농도、흡부시간적곡선진행의합。결과표명,후사충방정적의합도교호,저설명차흡부시복잡적비균상확산흡부과정,존재화학흡부,차막확산화과립내확산공동공제흡부속솔。
The removal of Safranine T from aqueous effluents by alginic acid fibre was studied.The kinetics of sorption were analyzed by six kinetic models of the Pseudo-first-order model,the exponential function model,the pseudo-second-order model,the intra-particle diffusion model,the Elovich kinetic equation,and the double-constant equation.The results showed that the last four models were applied to fit the experimental kinetic data.The adsorption was a complex heterogeneous diffusion process,with chemical adsorption.Intra-particle diffusion and extra-particle diffusion both controlled the adsorption rate.