CAJ | 학술논문

本文以二茂铁为原料,经独特的分子设计,将导电的共轭基团引入二茂铁高分子化合物中,再使分子中共轭基团和金属原子M配位,合成既含"磁性"基元的金属原子离域结构,又有"导电"基元的茂环和共轭取代基组成的大共轭体系的新一类高分子化合物.研究结果表明这种新型的二茂铁高分子材料具有较好的吸波性能.
본문이이무철위원료,경독특적분자설계,장도전적공액기단인입이무철고분자화합물중,재사분자중공액기단화금속원자M배위,합성기함"자성"기원적금속원자리역결구,우유"도전"기원적무배화공액취대기조성적대공액체계적신일류고분자화합물.연구결과표명저충신형적이무철고분자재료구유교호적흡파성능.
In this paper, ferrocene was used as raw material, the conjugated group bearing conductive function was introduced into ferrocenyl polymeric compound by means of special molecular designs.Then the conjugated group in molecular coordinated with different metallic atom M(Fe、Cr、Mn).Therefore, a new polymeric compound containing both metallic atom with delocalization structure of "magnetic" group and the conjugated system consisted of cyclopentadienide ring and conjugated substituent of the "conductive" group was synthesized.Results showed that the new ferrocenyl polymeric had good absorbing-wave performance relatively.