1,10-邻菲咯啉-铜(Ⅱ)-L-蛋氨酸配合物的合成、表征及其分子结构
1,10-린비각람-동(Ⅱ)-L-단안산배합물적합성、표정급기분자결구
Synthesis, Characterization and Crystal Structure of Ternary Cu (Ⅱ) Complex with 1, 10-Phenanthroline and L-Methioninate
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2002年 10期 1023-1027 ,共5页

    乐学义%童明良

    악학의%동명량

    1,10-邻菲咯啉 L-蛋氨酸 铜(Ⅱ)配合物 晶体结构 1,10-鄰菲咯啉 L-蛋氨痠 銅(Ⅱ)配閤物 晶體結構
    1,10-린비각람 L-단안산 동(Ⅱ)배합물 정체결구
    1,10-phenanthroline L-methioninate copper (Ⅱ) complex crystal structure


    The complex [Cu(L-met) (phen) (H20)] NO3 @ H20 has been synthesized and investigated by elementalanalysis, molar conductivity, spectroscopic and X-ray diffraction methods, where phen = 1, 10-phenanthroline andL-met = L-methioninate group. The complex crystallized in the monoclinic space group P21 with a = 12. 053 (2)A,b=6.886(1) A, c=13.385(3) A, β=113. 59(3)., V=1018.1(3) A3, Z=2, Dc=1.598g@ em-3, μ=1. 223mm-1, F(000) =506, R1 =0. 0306, and wR2=0. 0742. The copper (II) atom is ligated in a distortedsquare-pyramidal geometry by two nitrogen atoms of one phen and the amino nitrogen atom, one carboxylate oxygenatom of L-met in the base plane, and an aqua at the apical position. A one-dimensional chain configuration formedby the hydrogen-bonding and weak Cu-O (the uncoordinated carboxyl oxygen atom) coordination interactions be-tween neighboring [Cu(L-met) (phen) (H20) ] + cations. CCDC: 183368.
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