功能材料与器件学报
功能材料與器件學報
공능재료여기건학보
JOURNAL OF FUNCTIONAL MATERIALS AND DEVICES
2009年
1期
71-74
,共4页
武德起%YAO Jin-cheng%姚金城%赵红生%张东炎%常爱民%李锋%周阳
武德起%YAO Jin-cheng%姚金城%趙紅生%張東炎%常愛民%李鋒%週暘
무덕기%YAO Jin-cheng%요금성%조홍생%장동염%상애민%리봉%주양
高介电栅介质材料%激光分子束外延%二氧化铪
高介電柵介質材料%激光分子束外延%二氧化鉿
고개전책개질재료%격광분자속외연%이양화협
High-k gate dielectric%LMBE%HfO2
采用激光分子束外延法(LMBE)在P型Si(100)衬底上沉积了(HfO2)x(Al2O3)Y(NiO)1-x-y,栅介质薄膜,研究了其热稳定性以及阻挡氧扩散的能力.X射线衍射表明在HfO2中掺入Ni和Al元素明显提高了其结晶温度.原子力显微镜测试显示:在N2中退火后薄膜表面是原子级平滑连续的,没有发现针孔.900℃N2中退火后的薄膜在高分辨透射电镜下没有发现硅酸盐界面层.实验结果表明在氧化物薄膜与硅衬底之间引入Ni-Al-O置入层能够防止硅酸盐低介电界面层的生成,这有利于MOS晶体管的进一步尺度缩小.
採用激光分子束外延法(LMBE)在P型Si(100)襯底上沉積瞭(HfO2)x(Al2O3)Y(NiO)1-x-y,柵介質薄膜,研究瞭其熱穩定性以及阻擋氧擴散的能力.X射線衍射錶明在HfO2中摻入Ni和Al元素明顯提高瞭其結晶溫度.原子力顯微鏡測試顯示:在N2中退火後薄膜錶麵是原子級平滑連續的,沒有髮現針孔.900℃N2中退火後的薄膜在高分辨透射電鏡下沒有髮現硅痠鹽界麵層.實驗結果錶明在氧化物薄膜與硅襯底之間引入Ni-Al-O置入層能夠防止硅痠鹽低介電界麵層的生成,這有利于MOS晶體管的進一步呎度縮小.
채용격광분자속외연법(LMBE)재P형Si(100)츤저상침적료(HfO2)x(Al2O3)Y(NiO)1-x-y,책개질박막,연구료기열은정성이급조당양확산적능력.X사선연사표명재HfO2중참입Ni화Al원소명현제고료기결정온도.원자력현미경측시현시:재N2중퇴화후박막표면시원자급평활련속적,몰유발현침공.900℃N2중퇴화후적박막재고분변투사전경하몰유발현규산염계면층.실험결과표명재양화물박막여규츤저지간인입Ni-Al-O치입층능구방지규산염저개전계면층적생성,저유리우MOS정체관적진일보척도축소.
The thermal stability and the resistance to oxygen diffusion of (HfO2)x (Al2O3)y (NiO)1-x-y gate dielectrics deposited on p-type Si (100) substrate by laser molecular beam epitaxy technique (LMBE) have been investigated. X-ray diffraction (XRD) results indicate that the crystallization temperature sig-nificantly increases with Ni and Al added into the HfO2 film. Atomic force microscopy (AFM) testing shows that the surface of these films after annealing in N2 is continuous and flat at the atomic level with no pinhole observed. No silicate interracial layer is found in the high-resolution cross-section transmission electron microscope (HRTEM) images of the (HfO2)x( Al2O3)y(NiO)1-x-y films after 900℃ annealing in N2. It is indicated that the interposed layer of Ni-Al- O between the oxide film and the Si substrate ena-scale.