有色金属
有色金屬
유색금속
NONFERROUS METALS
2010年
1期
92-95
,共4页
环境工程%地热水除氟%电絮凝%机理
環境工程%地熱水除氟%電絮凝%機理
배경공정%지열수제불%전서응%궤리
environment engineering%fluoride removal from geothermal water%electric flocculation%mechanism
针对常用的除氟工艺存在的缺点,以高氟地热水处理为研究对象,研究利用电絮凝法除氟过程.结果表明,电絮凝法处理高氟地热水的最佳工艺参数为面体比80m~2/m~3、极板间距0.5cm和电流密度10A/m~2,电耗为2.13kWh/t,酸性或中性水和较高的水温有助于提高处理效果.电絮凝法除氟机理为可溶性的铝电解产生Al~(3+)离子在适宜的pH值时形成Al(OH)~3,最后转换成Al_n(OH)_(3n),通过絮凝作用将氟化物去除.
針對常用的除氟工藝存在的缺點,以高氟地熱水處理為研究對象,研究利用電絮凝法除氟過程.結果錶明,電絮凝法處理高氟地熱水的最佳工藝參數為麵體比80m~2/m~3、極闆間距0.5cm和電流密度10A/m~2,電耗為2.13kWh/t,痠性或中性水和較高的水溫有助于提高處理效果.電絮凝法除氟機理為可溶性的鋁電解產生Al~(3+)離子在適宜的pH值時形成Al(OH)~3,最後轉換成Al_n(OH)_(3n),通過絮凝作用將氟化物去除.
침대상용적제불공예존재적결점,이고불지열수처리위연구대상,연구이용전서응법제불과정.결과표명,전서응법처리고불지열수적최가공예삼수위면체비80m~2/m~3、겁판간거0.5cm화전류밀도10A/m~2,전모위2.13kWh/t,산성혹중성수화교고적수온유조우제고처리효과.전서응법제불궤리위가용성적려전해산생Al~(3+)리자재괄의적pH치시형성Al(OH)~3,최후전환성Al_n(OH)_(3n),통과서응작용장불화물거제.
According to shortcoming of commonly fluorine removal treatment technology, the fluorine removal process with electric flocculation is investigated with high fluoride geothermal water treatment as the research object. The result shows that the optimal parameters are area/volume ration80m~2/m~3, distance between polar plates 0.5cm, current density 10A/m~2, respectively. The power consumption is 2.13kWh/t. The result of treatment is improved by acid or neutral water and higher water temperature. The fluorine removal mechanism with electric flocculation is in suitable pH condition, Al(OH)~3 forming from soluble Al~(3+). The Al(OH)~3 are changed into Al_n (OH)_(3n) finally, fluoride are removed by flocculating function.