真空科学与技术学报
真空科學與技術學報
진공과학여기술학보
JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY
2010年
1期
1-5
,共5页
陈长青%丁明清%李兴辉%白国栋%张甫权%冯进军
陳長青%丁明清%李興輝%白國棟%張甫權%馮進軍
진장청%정명청%리흥휘%백국동%장보권%풍진군
UV光刻技术%变倾角缩口%定向碳纳米管的生长%场发射阵列冷阴极
UV光刻技術%變傾角縮口%定嚮碳納米管的生長%場髮射陣列冷陰極
UV광각기술%변경각축구%정향탄납미관적생장%장발사진렬랭음겁
UV lithography%Aperture reduction via varying glancing-angle%Growth of well-aligned carbon-nanotube%Field emission arrays cathode
通过普通的紫外(UV)光刻工艺,结合"变倾角缩口"新技术,研制了不同发射单元尺寸的碳纳米管(CNTs)阵列阴极.扫瞄电镜分析表明,随着缩口尺寸的依次减小(从0.6μm到0.4μm,最后到0.2μm),发射单元内CNTs的根数也不断减少.当孔径缩至0.2μm时,发射单元仅由1根~3根CNTs组成,并且大部分单元顶端均有单根CNT伸出,使得整个发射体近似于单根CNT.场发射特性测试结果表明,0.2μm发射单元尺寸的阵列阴极,开启电场约2V·μm~(-1);当场强为20V·μm~(-1)时,该阵列的电流密度达到0.35A·cm~(-2),比1μm尺寸的阵列阴极提高了近4倍,比连续生长的薄膜CNTs阴极则高1~2个数量级.
通過普通的紫外(UV)光刻工藝,結閤"變傾角縮口"新技術,研製瞭不同髮射單元呎吋的碳納米管(CNTs)陣列陰極.掃瞄電鏡分析錶明,隨著縮口呎吋的依次減小(從0.6μm到0.4μm,最後到0.2μm),髮射單元內CNTs的根數也不斷減少.噹孔徑縮至0.2μm時,髮射單元僅由1根~3根CNTs組成,併且大部分單元頂耑均有單根CNT伸齣,使得整箇髮射體近似于單根CNT.場髮射特性測試結果錶明,0.2μm髮射單元呎吋的陣列陰極,開啟電場約2V·μm~(-1);噹場彊為20V·μm~(-1)時,該陣列的電流密度達到0.35A·cm~(-2),比1μm呎吋的陣列陰極提高瞭近4倍,比連續生長的薄膜CNTs陰極則高1~2箇數量級.
통과보통적자외(UV)광각공예,결합"변경각축구"신기술,연제료불동발사단원척촌적탄납미관(CNTs)진렬음겁.소묘전경분석표명,수착축구척촌적의차감소(종0.6μm도0.4μm,최후도0.2μm),발사단원내CNTs적근수야불단감소.당공경축지0.2μm시,발사단원부유1근~3근CNTs조성,병차대부분단원정단균유단근CNT신출,사득정개발사체근사우단근CNT.장발사특성측시결과표명,0.2μm발사단원척촌적진렬음겁,개계전장약2V·μm~(-1);당장강위20V·μm~(-1)시,해진렬적전류밀도체도0.35A·cm~(-2),비1μm척촌적진렬음겁제고료근4배,비련속생장적박막CNTs음겁칙고1~2개수량급.
Four types of arrays of single carbon nanotubes (CNTs),with field emitter diameters of 1μm,0.6μm,0.4μm and 0.2μm,were fabricated,respectively,by combining conventional ultraviolet (UV) lithography and the recently-developed technique of "aperture reduction via varying glancing angle".The scanning electron microscopy images show that the number of CNTs in each emitter decreases with an reduction of the aperture size.For the arrays fabricated with the 0.2μm aperture,only 1~3CNTs were observed in each unit cell,while most emitters exhibit single ones,in addition,its onset field lowers to 2V·μm~(-1);and at a field of 20V·μm~(-1),its emission current density reaches 0.35A·cm~(-2),4 times higher than that of the 1.0μm CNTs emitter array and 1 to 2 order of magnitudes higher than that of the densely packed CNTs films.