环境工程学报
環境工程學報
배경공정학보
CHINESE JOURNAL OF ENVIRONMENTAL ENGINEERING
2010年
1期
21-26
,共6页
孔令才%周顺桂%赵华章%张宝刚%倪晋仁
孔令纔%週順桂%趙華章%張寶剛%倪晉仁
공령재%주순계%조화장%장보강%예진인
微生物燃料电池%阳极%高程差%水力停留时间
微生物燃料電池%暘極%高程差%水力停留時間
미생물연료전지%양겁%고정차%수력정류시간
microbial fuel cell%anode%difference in elevation%hydraulic retention time
微生物燃料电池(MFC)中输出电压/电流的提升,以及反应器体积的扩展放大是其工程化应用的关键.本文构建了一个总体积为6.4 L的新型厌氧折流板式微生物燃料电池堆(ABSMFC).以葡萄糖作为底物,探讨了阳极材料、液面高程差和水力停留时间(HRT)等因素对ABSMFC性能的影响.结果表明,碳纤维毡作为阳极时,电池单体外电路平均分压(R_(ex)=1 000 Ω)为210 mV,填充石墨颗粒后增加到319.8 mV.格室间存在液面高程差时,电池单体、串联和并联的功率密度分别为207.1、181.1和215.7 mW/m~2,当尤液面高程差(即水力相连)时为205.8、69.5和151.5 mW/m~2.4个电池单体串联和并联连接时,HRT对ABSMFC的产电稳定性无影响,溶解性COD的去除率和库仑效率均随HRT的增加而升高,且并联效果优于串联.
微生物燃料電池(MFC)中輸齣電壓/電流的提升,以及反應器體積的擴展放大是其工程化應用的關鍵.本文構建瞭一箇總體積為6.4 L的新型厭氧摺流闆式微生物燃料電池堆(ABSMFC).以葡萄糖作為底物,探討瞭暘極材料、液麵高程差和水力停留時間(HRT)等因素對ABSMFC性能的影響.結果錶明,碳纖維氈作為暘極時,電池單體外電路平均分壓(R_(ex)=1 000 Ω)為210 mV,填充石墨顆粒後增加到319.8 mV.格室間存在液麵高程差時,電池單體、串聯和併聯的功率密度分彆為207.1、181.1和215.7 mW/m~2,噹尤液麵高程差(即水力相連)時為205.8、69.5和151.5 mW/m~2.4箇電池單體串聯和併聯連接時,HRT對ABSMFC的產電穩定性無影響,溶解性COD的去除率和庫崙效率均隨HRT的增加而升高,且併聯效果優于串聯.
미생물연료전지(MFC)중수출전압/전류적제승,이급반응기체적적확전방대시기공정화응용적관건.본문구건료일개총체적위6.4 L적신형염양절류판식미생물연료전지퇴(ABSMFC).이포도당작위저물,탐토료양겁재료、액면고정차화수력정류시간(HRT)등인소대ABSMFC성능적영향.결과표명,탄섬유전작위양겁시,전지단체외전로평균분압(R_(ex)=1 000 Ω)위210 mV,전충석묵과립후증가도319.8 mV.격실간존재액면고정차시,전지단체、천련화병련적공솔밀도분별위207.1、181.1화215.7 mW/m~2,당우액면고정차(즉수력상련)시위205.8、69.5화151.5 mW/m~2.4개전지단체천련화병련련접시,HRT대ABSMFC적산전은정성무영향,용해성COD적거제솔화고륜효솔균수HRT적증가이승고,차병련효과우우천련.
To increase the power output simultaneously scale-up the reactor of microbial fuel cell (MFC) , a novel anaerobic baffled stacking microbial fuel cell ( ABSMFC ) was constructed with a total volume of 6.4 L. By using the glucose, the factors that affected the performance of MFC units, series and parallel stacks were studied, including anode electrode materials, liquid-level difference in elevation and hydraulic retention time (HRT). The results showed that the average voltage output of external resistance of 1 000 Ω was 210 mV using the carbon fiber felt as anode, and it reached 319. 8 mV once the graphite granules were added to the anodic chamber. In the case of liquid-level difference in elevation of four compartments, the average maximal power densities of four MFC units, series stack and parallel stack were 207.1 mW/m~2, 181.1 mW/m~2 and 215. 7 mW/ m~2, respectively, while they were 205.8 mW/m~2,69.5 mW/m~2 and 151.5 mW/m~2 without liquid-level difference in elevation. Both in the series and parallel stacks, the power output were kept stable with HRT increase, while the soluble COD and the Coulombic efficiency were increased with HRT increase,and the parallel stack had better performance than series stack.