粉末冶金技术
粉末冶金技術
분말야금기술
POWDER METALLURGY TECHNOLOGY
2009年
5期
341-345,350
,共6页
徐自伟%贾成厂%况春江%曲选辉
徐自偉%賈成廠%況春江%麯選輝
서자위%가성엄%황춘강%곡선휘
粉末注射成形%含氮无镍不锈钢%含氮量%力学性能%断口形貌%耐点蚀性能
粉末註射成形%含氮無鎳不鏽鋼%含氮量%力學性能%斷口形貌%耐點蝕性能
분말주사성형%함담무얼불수강%함담량%역학성능%단구형모%내점식성능
powder injection molding%nitrogen-containing nickel-free stainless steel%nitrogen content%mechanical properties%fracture morphology%pitting corrosion resistance
为了扩大不锈钢的应用范围与节省较昂贵的镍资源,笔者以粒径<38.5μm含氮不锈钢粉末和多组元粘结剂(PW,HDPE,SA)为原料,采用粉末注射成形工艺制备了0Cr17Mn12Mo2N含氮无镍奥氏体不锈钢材料,并对其表面状态与显微组织、拉伸断口形貌以及力学性能、耐蚀性能进行了分析与测试.结果表明:使用上述粘结剂能够成功地实现含氮不锈钢粉末的注射成形;在流动N2气氛中,0.1MPa,1340℃下烧结120min,再经热处理后,注射成形0Cr17Mn12Mo2N不锈钢烧结体的相对密度可达到97.6%,含氮量达到0.83%(质量分数).该含氮无镍不锈钢具有良好的强度和塑性:抗拉强度σ_b=910MPa,屈服强度σ_(0.2)=560MPa,伸长率δ_5=46%,断面收缩率Ф=39.5%,硬度(HRB)为91.7,各项性能指标均优异于MIM 316L不锈钢.
為瞭擴大不鏽鋼的應用範圍與節省較昂貴的鎳資源,筆者以粒徑<38.5μm含氮不鏽鋼粉末和多組元粘結劑(PW,HDPE,SA)為原料,採用粉末註射成形工藝製備瞭0Cr17Mn12Mo2N含氮無鎳奧氏體不鏽鋼材料,併對其錶麵狀態與顯微組織、拉伸斷口形貌以及力學性能、耐蝕性能進行瞭分析與測試.結果錶明:使用上述粘結劑能夠成功地實現含氮不鏽鋼粉末的註射成形;在流動N2氣氛中,0.1MPa,1340℃下燒結120min,再經熱處理後,註射成形0Cr17Mn12Mo2N不鏽鋼燒結體的相對密度可達到97.6%,含氮量達到0.83%(質量分數).該含氮無鎳不鏽鋼具有良好的彊度和塑性:抗拉彊度σ_b=910MPa,屈服彊度σ_(0.2)=560MPa,伸長率δ_5=46%,斷麵收縮率Ф=39.5%,硬度(HRB)為91.7,各項性能指標均優異于MIM 316L不鏽鋼.
위료확대불수강적응용범위여절성교앙귀적얼자원,필자이립경<38.5μm함담불수강분말화다조원점결제(PW,HDPE,SA)위원료,채용분말주사성형공예제비료0Cr17Mn12Mo2N함담무얼오씨체불수강재료,병대기표면상태여현미조직、랍신단구형모이급역학성능、내식성능진행료분석여측시.결과표명:사용상술점결제능구성공지실현함담불수강분말적주사성형;재류동N2기분중,0.1MPa,1340℃하소결120min,재경열처리후,주사성형0Cr17Mn12Mo2N불수강소결체적상대밀도가체도97.6%,함담량체도0.83%(질량분수).해함담무얼불수강구유량호적강도화소성:항랍강도σ_b=910MPa,굴복강도σ_(0.2)=560MPa,신장솔δ_5=46%,단면수축솔Ф=39.5%,경도(HRB)위91.7,각항성능지표균우이우MIM 316L불수강.
In order to enlarge the application scope of stainless steel and economize costly nickel resource, with nitrogen-containing stainless steel powder and binders PW, HDPE, SA as the raw materials, 0Cr17Mn12Mo2N alloyed steel were produced. Micro structure characteristic and fracture morphology of specimens sintered at various temperatures were investigated by OM and SEM, respectively. And mechanical properties of sintered specimens were determined by tensile test. When the specimens are sintered at 1 340℃ for 120 minutes in flowing N_2(0.1 Mpa) , the results show that the alloyed steel exhibits better property indexes than MIM 316L austenitic stainless steel. A favorable combination of the relative density of 97. 6% and the nitrogen content of 0. 83wt% can be obtained. After solution annealing, the yield strength σ_(0.2), ultimate tensile strength σ_b, elongation δ,, reduction of area Φ and hardness can reach 560 Mpa, 910 Mpa, 46% , 39. 5% and 91. 7 (HRB) , respectively.