CAJ | 학술논문

合成了钕-草酸-丙烯酸三元固体配合物.利用元素分析、红外光谱(FT-IR)、紫外-可见光谱(UV-Vis)、热重分析(TGA)和荧光光谱等手段研究了配合物的结构和性质.结果表明配合物的组成为[Nd(OOC-COO)(CH2CH-COO)]·3H2O,热分析结果表明该配合物具有较好的热稳定性.荧光光谱表明配合物都具有较好的荧光特性,且发射谱线很窄,主发射峰为钕离子的4G5/2+2G7/2-4I9/2跃迁,表明合成的新型稀土配合物可用作光致发光材料.
합성료녀-초산-병희산삼원고체배합물.이용원소분석、홍외광보(FT-IR)、자외-가견광보(UV-Vis)、열중분석(TGA)화형광광보등수단연구료배합물적결구화성질.결과표명배합물적조성위[Nd(OOC-COO)(CH2CH-COO)]·3H2O,열분석결과표명해배합물구유교호적열은정성.형광광보표명배합물도구유교호적형광특성,차발사보선흔착,주발사봉위녀리자적4G5/2+2G7/2-4I9/2약천,표명합성적신형희토배합물가용작광치발광재료.
The novel ternary solid complex of rare earth neodymium (Nd) with oxalic acid (OA) and acroleic acid (AA) was synthesized. The chemical structure and the properties of the complex were characterized by using the element analysis, FT-IR, UV-Vis spectrum, thermal gravimetric analysis (TGA) and fluorescence spectrum. Their composition was determined to be [Nd(OOC-COO) (CH2CH-COO)]·3H2O. The TGA result showed that the complex has excellent thermal stability. The fluorescence spectrum suggested that the innovative complex containing rare-earth ions (Nd3+), with strong characteristic emissions due to the 4G5/2+2G7/2-4I9/2 transition of Nd3+ ions, is a kind of photoluminescence materials.