现代化工
現代化工
현대화공
MODERN CHEMICAL INDUSTRY
2010年
1期
57-59
,共3页
黄智%李玉英%龙腾发%陈孟林%何星存
黃智%李玉英%龍騰髮%陳孟林%何星存
황지%리옥영%룡등발%진맹림%하성존
复合材料%Cu_2O%CNTs%光催化
複閤材料%Cu_2O%CNTs%光催化
복합재료%Cu_2O%CNTs%광최화
composite material%Cu_2O%CNTs%photocatalyst
以碳纳米管(CNTs)为载体,分别采用NaBH4、葡萄糖和水合肼3种不同还原剂制备Cu_2O/CNTs复合光催化剂,并表征了不同条件下制备的催化剂,同时考察了其对可溶性染料活性艳红X-3B的光催化活性.结果表明,葡萄糖还原法制备的Cu_2O颗粒均匀,晶型呈完整正八面体型,在可见光、75 min内可使质量浓度为100 mg/L、体积100 mL的X-3B脱色率达到72.4%,COD降解率达到66.7%.
以碳納米管(CNTs)為載體,分彆採用NaBH4、葡萄糖和水閤肼3種不同還原劑製備Cu_2O/CNTs複閤光催化劑,併錶徵瞭不同條件下製備的催化劑,同時攷察瞭其對可溶性染料活性豔紅X-3B的光催化活性.結果錶明,葡萄糖還原法製備的Cu_2O顆粒均勻,晶型呈完整正八麵體型,在可見光、75 min內可使質量濃度為100 mg/L、體積100 mL的X-3B脫色率達到72.4%,COD降解率達到66.7%.
이탄납미관(CNTs)위재체,분별채용NaBH4、포도당화수합정3충불동환원제제비Cu_2O/CNTs복합광최화제,병표정료불동조건하제비적최화제,동시고찰료기대가용성염료활성염홍X-3B적광최화활성.결과표명,포도당환원법제비적Cu_2O과립균균,정형정완정정팔면체형,재가견광、75 min내가사질량농도위100 mg/L、체적100 mL적X-3B탈색솔체도72.4%,COD강해솔체도66.7%.
By coating carbon nanotubes surface with Cu_2O three kinds of catalysts are prepared by reduction with hydrazine hydrate,sodium borohydride and glucose,respectively.The morphological structure of the photocatalysts is characterized,and their photocatalytic capabilities are tested by decomposing reactive brilliant red in the aqueous solution.The result shows that the Cu_2O/CNTs which is prepared by glucose has better effect than the other two,and it's a complete octahedral crystal shape with homogeneous granule dispersion and high purity.The photocatalytic degradation rate of reactive brilliant red (100 mg/L in 100 mL) can be 72.4% after 75 minutes,and the COD removal rate can be 66.7%.