玻璃钢/复合材料
玻璃鋼/複閤材料
파리강/복합재료
FIBER REINFORCED PLASTICS/COMPOSITES
2010年
2期
10-13
,共4页
郭建君%孙晋良%任慕苏%白瑞成
郭建君%孫晉良%任慕囌%白瑞成
곽건군%손진량%임모소%백서성
非等温DSC%Kinssinger方程%弯曲性能%断面形貌
非等溫DSC%Kinssinger方程%彎麯性能%斷麵形貌
비등온DSC%Kinssinger방정%만곡성능%단면형모
DSC%Kinssinger equation%three-point bending behavior%fracture appearance
对TDE-85和AG-80环氧树脂进行非等温DSC实验,采用热分析动力学Kinssinger方程对两种树脂体系的放热机理进行分析,得出TDE-85树脂体系的活化能为E=58.9kJ/mol,指前因子A=5.02×10~6s~(-1);AG-80树脂体系的活化能为E=50.4kJ/mol,指前因子A=3.99×10~6s~(-1).根据DSC升温曲线比较了两种树脂的放热起始温度、放热峰顶温度和结束温度,并以此确定了浇注体固化制度.对两种树脂的浇铸体进行弯曲性能测试,测试得出,TDE-85树脂体系浇铸体的弯曲模量达到1580.03MPa,弯曲强度为61.08MPa;AG-80树脂体系的弯曲模量达到了1804.32MPa,弯曲强度为42.64MPa.并采用高倍数码显微镜对断面进行观察,断面形貌显示,AG-80树脂浇铸体断面十分光滑而TDE-85树脂浇铸体断面存在大量水纹状裂纹.
對TDE-85和AG-80環氧樹脂進行非等溫DSC實驗,採用熱分析動力學Kinssinger方程對兩種樹脂體繫的放熱機理進行分析,得齣TDE-85樹脂體繫的活化能為E=58.9kJ/mol,指前因子A=5.02×10~6s~(-1);AG-80樹脂體繫的活化能為E=50.4kJ/mol,指前因子A=3.99×10~6s~(-1).根據DSC升溫麯線比較瞭兩種樹脂的放熱起始溫度、放熱峰頂溫度和結束溫度,併以此確定瞭澆註體固化製度.對兩種樹脂的澆鑄體進行彎麯性能測試,測試得齣,TDE-85樹脂體繫澆鑄體的彎麯模量達到1580.03MPa,彎麯彊度為61.08MPa;AG-80樹脂體繫的彎麯模量達到瞭1804.32MPa,彎麯彊度為42.64MPa.併採用高倍數碼顯微鏡對斷麵進行觀察,斷麵形貌顯示,AG-80樹脂澆鑄體斷麵十分光滑而TDE-85樹脂澆鑄體斷麵存在大量水紋狀裂紋.
대TDE-85화AG-80배양수지진행비등온DSC실험,채용열분석동역학Kinssinger방정대량충수지체계적방열궤리진행분석,득출TDE-85수지체계적활화능위E=58.9kJ/mol,지전인자A=5.02×10~6s~(-1);AG-80수지체계적활화능위E=50.4kJ/mol,지전인자A=3.99×10~6s~(-1).근거DSC승온곡선비교료량충수지적방열기시온도、방열봉정온도화결속온도,병이차학정료요주체고화제도.대량충수지적요주체진행만곡성능측시,측시득출,TDE-85수지체계요주체적만곡모량체도1580.03MPa,만곡강도위61.08MPa;AG-80수지체계적만곡모량체도료1804.32MPa,만곡강도위42.64MPa.병채용고배수마현미경대단면진행관찰,단면형모현시,AG-80수지요주체단면십분광활이TDE-85수지요주체단면존재대량수문상렬문.
The kinetics of the cure reaction for systems of TDE-85/MENA and AG-80/MENA epoxy resin was monitored by the differential scanning calorimetry(DSC) and investigated by the constant heating methods. According to the DSC graphs, the T-β graph extrapolation was used to get the characteristic curing process temperatures, and to confirm the technical parameters of the molding process of the resin system. The kinetic parameters of the curing re-action of TDE-85/MENA epoxy resin such as the overall activation energy E_a= 58.9kJ/mol, the frequency factor A =5.02 × 10~6s~(-1) ; Besides,the kinetic parameters of AG-80/MENA epoxy resin such as the overall activation energy E_a =50. 4kJ/mol,the frequency factor A =3.99 × 10~6s~(-1). The bending modulus of TDE-85/MENA epoxy resin east is 1580. 03MPa, and the bending strength of it is 61.08MPa. By comparison ,the bending modulus of AG-80/MENA epoxy resin cast is 1804. 32MPa, and the bending strength of it is 42. 64MP. From the photos of the fracture appearance, it has been confirmed that the fracture of AG-80/MENA epoxy resin cast is smooth,and the TDE-85/MENA epoxy resin cast is rough,there are a large number of cracks on it.