物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2011年
10期
2385-2392
,共8页
刘妍%卫中领%杨富巍%张昭
劉妍%衛中領%楊富巍%張昭
류연%위중령%양부외%장소
阳极氧化%环保型电解液%镁合金%对苯二甲酸%耐腐蚀性能
暘極氧化%環保型電解液%鎂閤金%對苯二甲痠%耐腐蝕性能
양겁양화%배보형전해액%미합금%대분이갑산%내부식성능
Anodizing%Environmentally friendly electrolyte%Magnesium alloy%Terephthalic acid%Corrosion resistance
研究了硼砂-对苯二甲酸环保型电解液中AZ91D镁合金的阳极氧化.考察了对苯二甲酸对镁合金阳极氧化过程及其氧化膜性能的影响,并利用扫描电镜(SEM)、X射线衍射(XRD)、能量散射谱(EDS)、动电位极化和电化学交流阻抗谱(EIS)等进行了分析表征.结果表明,对苯二甲酸的浓度对阳极氧化成膜过程、氧化膜的表面形貌、厚度、相结构和耐腐蚀性能都有重要影响.在硼酸盐电解液中加入适量的对苯二甲酸后,氧化电流密度降低,过度放电现象受到了明显的抑制,所制得的阳极氧化膜的质量也有了显著改善.氧化膜表面变得光滑、致密,膜厚度略有降低.氧化膜与镁合金基底的结合更紧密,而且其耐腐蚀性能也得到了明显增强.该研究对于镁合金阳极氧化处理工艺的环保化及阳极氧化膜质量的提高都具有积极意义.
研究瞭硼砂-對苯二甲痠環保型電解液中AZ91D鎂閤金的暘極氧化.攷察瞭對苯二甲痠對鎂閤金暘極氧化過程及其氧化膜性能的影響,併利用掃描電鏡(SEM)、X射線衍射(XRD)、能量散射譜(EDS)、動電位極化和電化學交流阻抗譜(EIS)等進行瞭分析錶徵.結果錶明,對苯二甲痠的濃度對暘極氧化成膜過程、氧化膜的錶麵形貌、厚度、相結構和耐腐蝕性能都有重要影響.在硼痠鹽電解液中加入適量的對苯二甲痠後,氧化電流密度降低,過度放電現象受到瞭明顯的抑製,所製得的暘極氧化膜的質量也有瞭顯著改善.氧化膜錶麵變得光滑、緻密,膜厚度略有降低.氧化膜與鎂閤金基底的結閤更緊密,而且其耐腐蝕性能也得到瞭明顯增彊.該研究對于鎂閤金暘極氧化處理工藝的環保化及暘極氧化膜質量的提高都具有積極意義.
연구료붕사-대분이갑산배보형전해액중AZ91D미합금적양겁양화.고찰료대분이갑산대미합금양겁양화과정급기양화막성능적영향,병이용소묘전경(SEM)、X사선연사(XRD)、능량산사보(EDS)、동전위겁화화전화학교류조항보(EIS)등진행료분석표정.결과표명,대분이갑산적농도대양겁양화성막과정、양화막적표면형모、후도、상결구화내부식성능도유중요영향.재붕산염전해액중가입괄량적대분이갑산후,양화전류밀도강저,과도방전현상수도료명현적억제,소제득적양겁양화막적질량야유료현저개선.양화막표면변득광활、치밀,막후도략유강저.양화막여미합금기저적결합경긴밀,이차기내부식성능야득도료명현증강.해연구대우미합금양겁양화처리공예적배보화급양겁양화막질량적제고도구유적겁의의.
Anodizing a AZ91D magnesium alloy in environmentally friendly borate-terephthalic acid (TPA)electrolyte was studied.The effect of TPA on the anodizing process and the properties of the resultant anodized film were investigated by scanning electron microscopy (SEM),X-ray diffraction (XRD),energy dispersive spectrometry (EDS),potentiodynamic polarization,and electrochemical impedance spectroscopy (EIS).The results showed that the anodizing process,the surface morphology,thickness,phase structure,and corrosion resistance of the anodized film were strongly dependent on the concentration of TPA.In the presence of adequate TPA,a moderate anodizing process was obtained.The currant density of the anodizing process was reduced and excessive sparking in the anodizing process was obviously inhibited.In the presence of TPA,the quality of the anodized film improved.The film became more compact and smooth in structure.The thickness of the film decreased slightly.The interface between the anodized film and the magnesium substrate became indistinct indicating a better adhesion between them.The corrosion resistance of the anodized film was obviously enhanced.From these highly positive results,TPA can be used as an effective additive for the anodizing treatment of magnesium alloy.The proposed anodizing process is of importance to make the existing anodizing process `greener' and to improve the quality of the anodized film.