中国科技论文在线
中國科技論文在線
중국과기논문재선
SCIENCEPAPER ONLINE
2011年
9期
665-668
,共4页
微针阵列%管道刻蚀%玻璃纤维%管道阵列
微針陣列%管道刻蝕%玻璃纖維%管道陣列
미침진렬%관도각식%파리섬유%관도진렬
needle arrays%tube etching%glass fibers%tube arrays
以E玻璃纤维为模板,通过聚合物灌注、切片和化学腐蚀、聚合物去除等步骤,获得了大面积、形貌一致的针状微结构阵列。利用SEM等对其形貌进行了表征,结果表明,在不存在微流体对流行为的条件下依然可以形成针状形貌。据此探讨了玻璃微针的形成机理,认为E玻璃纤维微针阵列的形成是受限于空间(如微腔等)中反应物和生成物的扩散行为。这为微纳受限空间中固体腐蚀反应行为动力学的进一步研究提供了实验证据,同时也拓展了E玻璃纤维的应用领域。
以E玻璃纖維為模闆,通過聚閤物灌註、切片和化學腐蝕、聚閤物去除等步驟,穫得瞭大麵積、形貌一緻的針狀微結構陣列。利用SEM等對其形貌進行瞭錶徵,結果錶明,在不存在微流體對流行為的條件下依然可以形成針狀形貌。據此探討瞭玻璃微針的形成機理,認為E玻璃纖維微針陣列的形成是受限于空間(如微腔等)中反應物和生成物的擴散行為。這為微納受限空間中固體腐蝕反應行為動力學的進一步研究提供瞭實驗證據,同時也拓展瞭E玻璃纖維的應用領域。
이E파리섬유위모판,통과취합물관주、절편화화학부식、취합물거제등보취,획득료대면적、형모일치적침상미결구진렬。이용SEM등대기형모진행료표정,결과표명,재불존재미류체대류행위적조건하의연가이형성침상형모。거차탐토료파리미침적형성궤리,인위E파리섬유미침진렬적형성시수한우공간(여미강등)중반응물화생성물적확산행위。저위미납수한공간중고체부식반응행위동역학적진일보연구제공료실험증거,동시야탁전료E파리섬유적응용영역。
Using E-glass fibers as templates,a highly aligned needle arrays has been created over large area by simple processes of polymer infiltration,cutting,chemical etching and polymer removal.The sizes and shapes of the array were characterized by scanning electron microscope(SEM).The results showed that the formation of micro-needles was independent on the fluid convection necessarily.The possible mechanism of the needle formation was studied.It is believed that the needle shape was originated from the confuse behavior of the reactants and resultants.This research provides experimental evidence for further study the solid etching concealed in tiny space.It also extendes the possible application area of the E-glass fibers.