CAJ | 학술논문

建立渔业水质中七氟菊酯、联苯菊酯、甲氰菊酯、三氟氯氰菊酯、氯菊酯、氟氯氰菊酯、氯氰菊酯、氰戊菊酯、氟胺氰菊酯、溴氰菊酯10种拟除虫菊酯残留的分析方法。样品以石油醚萃取、无水硫酸钠脱水、减压浓缩后用气相色谱-电子捕获检测器（GC-ECD）测定。七氟菊酯在2.5～100ng/mL、其它9种菊酯在5～200ng/mL内线性关系良好（r≥0.9954）;0.05μg/L、0.5μg/L、1μg/L添加浓度水平的回收率在73.8%～100.2%之间,相对标准偏差（RSD）为2.53%～10.3%;检出限（LOD）为0.125～2.5ng/L,最低定量限（LOQ）为0.025～0.05μg/L。该方法简单快速、准确可靠,能满足渔业水质拟除虫菊酯污染的检测要求。
건립어업수질중칠불국지、련분국지、갑청국지、삼불록청국지、록국지、불록청국지、록청국지、청무국지、불알청국지、추청국지10충의제충국지잔류적분석방법。양품이석유미췌취、무수류산납탈수、감압농축후용기상색보-전자포획검측기（GC-ECD）측정。칠불국지재2.5～100ng/mL、기타9충국지재5～200ng/mL내선성관계량호（r≥0.9954）;0.05μg/L、0.5μg/L、1μg/L첨가농도수평적회수솔재73.8%～100.2%지간,상대표준편차（RSD）위2.53%～10.3%;검출한（LOD）위0.125～2.5ng/L,최저정량한（LOQ）위0.025～0.05μg/L。해방법간단쾌속、준학가고,능만족어업수질의제충국지오염적검측요구。
A method for determining tefluthrin,bifenthrin,fenpropathrin,cyhalothrin,permethrin,cyfluthrin,cypermethrin,fenvalerate,tau-fluvalinate,deltamethrin residues in fishery water was developed.The pyrethroids were extracted by petroleum ether,dehydrated by anhydrous sodium sulfate,concentrated and then analyzed by gas chromatography with electron capture detector（GC-ECD）.The linear range of tefluthrin was 2.5～100ng/mL and the other nine were 5～200ng/mL（r≥0.9954）.When spiked with 0.05μg/L,0.5μg/L,1μg/L,the average recoveries ranged from 73.8% to 100.2% and their relative standard deviations（RSD）were between 2.53% and 10.3%.The limits of detection（LOD） and limits of quantitation（LOQ） for all pyrethroids were in the range from 0.125～2.5ng/L and 0.025～0.05μg/L separately.This method is simple,reliable and can be applied in the detection of pyrethroid in fishery water.