潍坊学院学报
濰坊學院學報
유방학원학보
JOURNAL OF WEIFANG UNIVERSITY
2011年
6期
53-57
,共5页
光催化降解%分散染料%二氧化钛%动力学
光催化降解%分散染料%二氧化鈦%動力學
광최화강해%분산염료%이양화태%동역학
photocatalytic degradation%dispersing dyestuff%TiO2%kinetics
本文以活性炭负载二氧化钛为光催化剂,在紫外灯照射下对分散染料溶液进行光催化降解实验研究。通过改变光催化剂用量、溶液pH、溶液的初始浓度,探讨了光催化降解两种分散染料的规律,进一步运用Langmuir—Hinshelwood力学方程对两种染料降解动力学规律进行了研究。结果表明,分散深蓝溶液浓度在2.5mg/L,分散翠蓝溶液浓度在8mg/L时,染料适宜pH值均为4,催化剂投入量为1g/L,此时降解效果最好,二者的光催化反应均符合一级动力学规律。
本文以活性炭負載二氧化鈦為光催化劑,在紫外燈照射下對分散染料溶液進行光催化降解實驗研究。通過改變光催化劑用量、溶液pH、溶液的初始濃度,探討瞭光催化降解兩種分散染料的規律,進一步運用Langmuir—Hinshelwood力學方程對兩種染料降解動力學規律進行瞭研究。結果錶明,分散深藍溶液濃度在2.5mg/L,分散翠藍溶液濃度在8mg/L時,染料適宜pH值均為4,催化劑投入量為1g/L,此時降解效果最好,二者的光催化反應均符閤一級動力學規律。
본문이활성탄부재이양화태위광최화제,재자외등조사하대분산염료용액진행광최화강해실험연구。통과개변광최화제용량、용액pH、용액적초시농도,탐토료광최화강해량충분산염료적규률,진일보운용Langmuir—Hinshelwood역학방정대량충염료강해동역학규률진행료연구。결과표명,분산심람용액농도재2.5mg/L,분산취람용액농도재8mg/L시,염료괄의pH치균위4,최화제투입량위1g/L,차시강해효과최호,이자적광최화반응균부합일급동역학규률。
Photocatalytic degradation of two--type dyestuffs waste water (S--3BG and S--GL)have been investigated using titanium dioxide supported on active carbon, with various factors, just like dosage of photocatalyst, pH value of the solution, initial concentration of dye solution. From the experimental results of photocatalytic degradation of S--3BG and S--GL, the conclusions can be attained that, the S--3BG concentration at 2. 5 mg/L or S--GL concentration at 8mg/L, pH value being 4, the photoeatalyst dosage at 1 g/L, the photoeatalytic degradation effieiencies were approximated to the maximum values, further, the photocatalyses of them were the apparent first--order kinetic reaction.