山东轻工业学院学报：自然科学版
山東輕工業學院學報：自然科學版
산동경공업학원학보：자연과학판
Journal of Shandong Institute of Light Industry(Natural Science Edition)
2011年
3期
25-29
,共5页
混合酸酐%海藻纤维%自制纺丝机%响应面法%人体模拟汗液
混閤痠酐%海藻纖維%自製紡絲機%響應麵法%人體模擬汗液
혼합산항%해조섬유%자제방사궤%향응면법%인체모의한액
mixed anhydride%alginate fiber%self-made wet-spinning machine%RSM%artificial perspiration
将海藻酸钠与不同浓度和配比的混合酸酐在一定条件下进行交联反应,制得不同的交联海藻酸钠,再将交联海藻酸钠用自制简易湿法纺丝机经氯化钙凝固浴制成交联海藻纤维,并测纤维强度。配制人体模拟汗液,测定交联海藻纤维对汗液的吸湿性。用响应面法以交联海藻纤维强度及对模拟人体汗液的吸湿性能两部分为指标,对增强型混酐海藻纤维的最佳合成条件进行探讨分析,结果发现最佳合成条件为：混合酸酐的总量占绝干海藻酸钠质量的比重为3.78%、乙酸酐占混合酸酐的质量比重为9.03%、交联反应温度为59.98℃,交联海藻纤维的断裂强度为18.55cN/tex。对模拟人体汗液的吸湿率为2.00%。
將海藻痠鈉與不同濃度和配比的混閤痠酐在一定條件下進行交聯反應,製得不同的交聯海藻痠鈉,再將交聯海藻痠鈉用自製簡易濕法紡絲機經氯化鈣凝固浴製成交聯海藻纖維,併測纖維彊度。配製人體模擬汗液,測定交聯海藻纖維對汗液的吸濕性。用響應麵法以交聯海藻纖維彊度及對模擬人體汗液的吸濕性能兩部分為指標,對增彊型混酐海藻纖維的最佳閤成條件進行探討分析,結果髮現最佳閤成條件為：混閤痠酐的總量佔絕榦海藻痠鈉質量的比重為3.78%、乙痠酐佔混閤痠酐的質量比重為9.03%、交聯反應溫度為59.98℃,交聯海藻纖維的斷裂彊度為18.55cN/tex。對模擬人體汗液的吸濕率為2.00%。
장해조산납여불동농도화배비적혼합산항재일정조건하진행교련반응,제득불동적교련해조산납,재장교련해조산납용자제간역습법방사궤경록화개응고욕제성교련해조섬유,병측섬유강도。배제인체모의한액,측정교련해조섬유대한액적흡습성。용향응면법이교련해조섬유강도급대모의인체한액적흡습성능량부분위지표,대증강형혼항해조섬유적최가합성조건진행탐토분석,결과발현최가합성조건위：혼합산항적총량점절간해조산납질량적비중위3.78%、을산항점혼합산항적질량비중위9.03%、교련반응온도위59.98℃,교련해조섬유적단렬강도위18.55cN/tex。대모의인체한액적흡습솔위2.00%。
Cross-linking reaction of Sodium alginate（SA） and mixed anhydride with different concentrations was occurred under certain conditions,then the cross-linking alginate fiber was prepared by wet-spinning in coagulation bath with the self-made wet-spinning machine.Prepared the artificial perspiration,and made a test on the hygroscopic of the fiber,then experimental scheme was designed by RSM.Finally,we got the enhanced mixed anhydride alginate fiber with the strength of 18.55 cN/tex,should be spun at the conditions as follows：The mass dosage of mixed anhydride to the dry SA was 3.78%,and the mass dosage of the acetic hydride to the mixed anhydride was 9.03%,the temperature of the Cross-linking reaction was 59.98 ℃,then,the fiber has the hygroscopic of 2.00% on artificial perspiration.
