[(n-C16-H33)N(CH3)3]2[TiF6]·2H2O的合成、结构和热稳定性
[(n-C16-H33)N(CH3)3]2[TiF6]·2H2O적합성、결구화열은정성
Synthesis, Structure and Thermal Property of [(n-C16H33N)N(CH3)3]2[TiF6]·2H2O
  • 万方数据
    物理化学学报 물이화학학보
    ACTA PHYSICO-CHIMICA SINICA
    2008年 11期 1945-1949 ,共5页

    刘国奇%李国宝%廖复辉%林建华

    류국기%리국보%료복휘%림건화

    氟钛酸盐%十六烷基三甲基胺%水热反应 氟鈦痠鹽%十六烷基三甲基胺%水熱反應
    불태산염%십륙완기삼갑기알%수열반응
    Titanium fluoride%Cetyltrimethylammonium%Hydrothermal reaction
    利用水热法在150℃合成了新的化合物六氟钛酸十六烷基三甲基胺二水合物([(n-C16H33)N(CH3)32[TiF6]·2H2O),并利用单晶X射线衍射技术解析了其结构,同时利用傅立叶变换红外光谱、元素分析及热分析技术加以佐证.该化合物由六氟钛酸根离子(TiF2-6)、水分子及十六烷基三甲基胺离子([(n-C16H33N(CH3)3]+)组成,属于单斜晶系,其空间群为C2/c.氢键在其构筑三维结构时起着重要的作用.
    이용수열법재150℃합성료신적화합물륙불태산십륙완기삼갑기알이수합물([(n-C16H33)N(CH3)32[TiF6]·2H2O),병이용단정X사선연사기술해석료기결구,동시이용부립협변환홍외광보、원소분석급열분석기술가이좌증.해화합물유륙불태산근리자(TiF2-6)、수분자급십륙완기삼갑기알리자([(n-C16H33N(CH3)3]+)조성,속우단사정계,기공간군위C2/c.경건재기구축삼유결구시기착중요적작용.
    A new compound dicetyltrmethylammonium hexafluorotitanium dihydrate, [(n-C16H33)N(CH3)3]2[TiF6]· 2H2O (compound 1), was hydrothermally synthesized at 150℃ and characterized by single crystal X-ray diffraction, Fourier-transform infrared (FTIR) spectroscopy, elemental analysis, and thermogravimetric analysis. Compound 1 crystallizes in the monoclinic system, space group C2/c. It consists of hexafluorotitanium cations [TiF6]2-, water molecular (H2O), and cetyltrimethylammonium ions [(n-C16H33)N(CH3)3]+, which are connected together by extensive hydrogen bonding.
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