无机材料学报
無機材料學報
무궤재료학보
JOURNAL OF INORGANIC MATERIALS
2000年
6期
1061-1066
,共6页
廖源%尚乃贵%李灿华%王冠中%马玉蓉%方容川
廖源%尚迺貴%李燦華%王冠中%馬玉蓉%方容川
료원%상내귀%리찬화%왕관중%마옥용%방용천
金刚石薄膜%横向偏压%原位光发射谱%非晶碳层
金剛石薄膜%橫嚮偏壓%原位光髮射譜%非晶碳層
금강석박막%횡향편압%원위광발사보%비정탄층
diamond film%transverse bias%in situ optical emission spectroscopy%amorphous carbon layer
利用热丝CVD方法研究了横向偏压对金刚石薄膜成核和生长的影响.实验表明,随着偏流的增加,金刚石在光滑硅衬底上的成核密度得到显著提高,最高可达1.1×108cm-2,但是横向偏压不利于金刚石薄膜的生长.原位光发射谱研究发现,横向偏流的增加提高了原子氢和CH基团的浓度,导致衬底表面非晶碳层的形成,这可能是造成横向偏压促进金刚石成核却不利于金刚石薄膜生长的主要原因.
利用熱絲CVD方法研究瞭橫嚮偏壓對金剛石薄膜成覈和生長的影響.實驗錶明,隨著偏流的增加,金剛石在光滑硅襯底上的成覈密度得到顯著提高,最高可達1.1×108cm-2,但是橫嚮偏壓不利于金剛石薄膜的生長.原位光髮射譜研究髮現,橫嚮偏流的增加提高瞭原子氫和CH基糰的濃度,導緻襯底錶麵非晶碳層的形成,這可能是造成橫嚮偏壓促進金剛石成覈卻不利于金剛石薄膜生長的主要原因.
이용열사CVD방법연구료횡향편압대금강석박막성핵화생장적영향.실험표명,수착편류적증가,금강석재광활규츤저상적성핵밀도득도현저제고,최고가체1.1×108cm-2,단시횡향편압불리우금강석박막적생장.원위광발사보연구발현,횡향편류적증가제고료원자경화CH기단적농도,도치츤저표면비정탄층적형성,저가능시조성횡향편압촉진금강석성핵각불리우금강석박막생장적주요원인.
The nucleation and growth of diamond film under transverse bias was investigated in a hot-filament chemical vapor deposition system. It was shown that the nucleation density of diamond is enhanced with the increasing of transverse bias current. A nucleation density of 1.1×.10 8cm-2 can be obtained, but transverse bias is harmful to the growth of diamond film.In situ optical emission spectroscopy technology was used to study the diamond film deposition process. The results showed that the improvement of the nucleation density and the harm of the growth may be caused by the abundance of atomic hydrogen and CH radical which is favorable to the formation of thin amorphous carbon layers.