无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2009年
4期
742-745
,共4页
王君%马运声%袁荣鑫%谢吉民
王君%馬運聲%袁榮鑫%謝吉民
왕군%마운성%원영흠%사길민
合成%表征%锰%环己烷甲酸根
閤成%錶徵%錳%環己烷甲痠根
합성%표정%맹%배기완갑산근
synthesis%characterization%manganese%cyclohexanecarboxylate
Complex[Mn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid)was synthesized group P1,with a=1.008 8(2)nm,b=1.086 3(1)nm,c=1.1649(3)nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V=1.125 4(4)nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mnl and Mn2 are bridged by cyelohexanecarboxylate ligands into a chain and the chains are further linked together bv 4.4'-bipy into a 2D plane.CCDC:692247.
