1,4-二(2′-芳基-1′,3′,4′-二唑基)-1,3-丁二烯的合成与性质
1,4-이(2′-방기-1′,3′,4′-이서기)-1,3-정이희적합성여성질
Synthesis and properties of 1,4-bis(2′-phenyl-1′,3′,4′-oxadiazole)-1,3-butadiene
  • 万方数据
    化学试剂 화학시제
    CHEMICAL REAGENTS
    2009年 12期 989-991,1033 ,共4页

    刘定军%李小康%范小林%张熊禄

    류정군%리소강%범소림%장웅록

    1,3,4-二唑%合成%性质 1,3,4-二唑%閤成%性質
    1,3,4-이서%합성%성질
    1,3,4-oxadiazole%synthesis%property
    以自制的N,N-二酰基肼在SOCl_2作用下脱水环化.合成了6个1,4-二(2′-芳基-1′,3′,4′-二唑基)-1,3-丁二烯类化合物,通过 ~1HNMR、FT-IR和MS对其结构进行表征.研究了它们的紫外-可见吸收光谱和荧光光谱.结果表明:在 336～350 nm出现最大吸收,发射强的蓝色荧光,最大发射峰出现在390～477 nm,是一类稳定的蓝光发光材料.
    이자제적N,N-이선기정재SOCl_2작용하탈수배화.합성료6개1,4-이(2′-방기-1′,3′,4′-이서기)-1,3-정이희류화합물,통과 ~1HNMR、FT-IR화MS대기결구진행표정.연구료타문적자외-가견흡수광보화형광광보.결과표명:재 336～350 nm출현최대흡수,발사강적람색형광,최대발사봉출현재390～477 nm,시일류은정적람광발광재료.
    Six novel 1,4-bis(2′-phenyl-1′,3′,4′-oxadiazole)-1,3-butadiene compounds were synthesized via cyclization of SOCl_2 with N,N′-diacylhydrazines.The structures of these compounds were characterized by ~1HNMR,FT-IR and MS.The UV-Vis spectroscopy and fluorescence spectroscopy of the said compounds were studied,the results showed that the maximum absorptive wavelength was detected at 336～350 nm,and the maximum emissive wavelength of polyamides ranged from 390～477 nm.The test results showed that the target compounds were a kind of stable blue luminescent materials.
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