CAJ | 학술논문

四羧酸对称取代的卟啉衍生物5，10，15，20-tetra-4-oxy(acetic acid)phenyl porphyrin(TAPP)及其与二甲基二(十六烷基)溴化铵(DMDHA)所形成的复合物在空气/水溶液界面上可形成稳定的单层膜.利用π-A等温线、UV-vis光谱及偏振光谱对单层膜的结构作了研究.结果表明，纯TAPP的单层膜中，卟啉环间有强的相互作用，其间距约为0.55 nm；1：1(摩尔比)的复合物单层膜中，环间距离与纯TAPP相比无明显变化，但聚集体间距离增加了；而1：4的复合物单层膜中，环与环间的相互作用减弱，环间距离及聚集体间的距离均明显增加.
사최산대칭취대적계람연생물5，10，15，20-tetra-4-oxy(acetic acid)phenyl porphyrin(TAPP)급기여이갑기이(십륙완기)추화안(DMDHA)소형성적복합물재공기/수용액계면상가형성은정적단층막.이용π-A등온선、UV-vis광보급편진광보대단층막적결구작료연구.결과표명，순TAPP적단층막중，계람배간유강적상호작용，기간거약위0.55 nm；1：1(마이비)적복합물단층막중，배간거리여순TAPP상비무명현변화，단취집체간거리증가료；이1：4적복합물단층막중，배여배간적상호작용감약，배간거리급취집체간적거리균명현증가.
Monolayers of 5,10,15,20-tetra-4-oxy(acetic acid)phenyl porphyrin (TAPP) and TAPP/Dimethyldihexadecylammonium bromide (DMDHA) (molar ratio: 1: 1, 1:4) at the air/liquid interface and onquartz plates have been studied by using π-A isotherms, UV- vis spectra and polarized UV-vis spectra.The interaction between porphyrin rings is stronger in pure TAPP monolayer, and the distance between the macrocycles was deduced to be about 0.55 nm. The distance between the macrocycles does not change obviously in the 1: 1 complex monolayer, but the distance between the adjacent aggregates increased. In the 1:4 complex monolayer, the distances between the macrocycles in the same aggregate and between the adjacent aggregates increased significantly, and the interactions between porphyrin rings became weaker.