CAJ | 학술논문

合成了中位带有不同取代基的锰corrole配合物1-Mn,2-Mn,3-Mn,4-Mn,并研究了其酸解和还原脱金属特性.结果表明取代基的性质对脱金属产率有很大的影响.缺电子金属锰corrole的酸解脱金属产率比富电子金属锰corrole高,而还原脱金属产率的顺序则正好相反.
합성료중위대유불동취대기적맹corrole배합물1-Mn,2-Mn,3-Mn,4-Mn,병연구료기산해화환원탈금속특성.결과표명취대기적성질대탈금속산솔유흔대적영향.결전자금속맹corrole적산해탈금속산솔비부전자금속맹corrole고,이환원탈금속산솔적순서칙정호상반.
Manganese (Ⅲ) corroles bearing different meso- substituents 1-Mn, 2-Mn, 3-Mn, 4-Mn have been synthesized and tested for the demetalation by using H2SO4/HAc and CH2Cl2/SnCl2(HCI) method. The demetalation yields depend on the substituents of corrole macrocycle significantly. Demetalation yield of electron-deficient Mn(Ⅲ) corrole is higher than electron-rich Mn(Ⅲ) corrole when using H2SO4/HAc method. But when using CH2Cl2/SnCl2 (HCl) reductive method, electron-rich Mn(Ⅲ) corrole gives higher demetalation yield.