玻璃钢/复合材料
玻璃鋼/複閤材料
파리강/복합재료
FIBER REINFORCED PLASTICS/COMPOSITES
2009年
4期
39-41,52
,共4页
彭瑛%刘建华%刘敏%雷玉龙
彭瑛%劉建華%劉敏%雷玉龍
팽영%류건화%류민%뢰옥룡
不饱和树脂%腐蚀%力学性能
不飽和樹脂%腐蝕%力學性能
불포화수지%부식%역학성능
unsaturated polyester resin%corrosion%mechanical properties
采用10%氢氧化钠、20%硫酸、甲苯分别对Ca(OH)2和Al(OH)3为填料的不饱和树脂聚合物浸泡,浸泡期分别为15、30、60天,测定其抗弯强度并进行力学性能分析.结果表明,随着腐蚀液浸泡时间的延长,其抗弯强度和抗压强度迅速下降.由显微镜对人造石浸泡后的观察表明.腐蚀主要是针对不饱和树脂聚合物发生,使聚合物与填料之间的粘接力降低.甲苯对不饱和树脂聚合物的腐蚀作用较大,氢氧化钠的腐蚀作用次之,而硫酸的腐蚀作用相对较小.
採用10%氫氧化鈉、20%硫痠、甲苯分彆對Ca(OH)2和Al(OH)3為填料的不飽和樹脂聚閤物浸泡,浸泡期分彆為15、30、60天,測定其抗彎彊度併進行力學性能分析.結果錶明,隨著腐蝕液浸泡時間的延長,其抗彎彊度和抗壓彊度迅速下降.由顯微鏡對人造石浸泡後的觀察錶明.腐蝕主要是針對不飽和樹脂聚閤物髮生,使聚閤物與填料之間的粘接力降低.甲苯對不飽和樹脂聚閤物的腐蝕作用較大,氫氧化鈉的腐蝕作用次之,而硫痠的腐蝕作用相對較小.
채용10%경양화납、20%류산、갑분분별대Ca(OH)2화Al(OH)3위전료적불포화수지취합물침포,침포기분별위15、30、60천,측정기항만강도병진행역학성능분석.결과표명,수착부식액침포시간적연장,기항만강도화항압강도신속하강.유현미경대인조석침포후적관찰표명.부식주요시침대불포화수지취합물발생,사취합물여전료지간적점접력강저.갑분대불포화수지취합물적부식작용교대,경양화납적부식작용차지,이류산적부식작용상대교소.
Unsaturated polyester resin artificial marble with the fillers of Ca(OH)2 and AI(OH)3 were soaked by 10% NaOH, 20% H2SO4 and toluene by 15, 30, 60 days. The flexural strength was mensurated and the mechanical properties was analyzed. The results showed that flexural strength was reduced rapidly with prolonging of the soaking time in corrosion solutions. The artificial marble soaked into corrosion solutions was observed by microscope. The observations showed that corrosion was dead against the polymer of unsaturated polyester resin, and the cohesive force between the polymer and fillers was reduced. The results of corrosive tests showed that toluene as organic solvent had a corrosion strong effect on polymer of unsaturated polyester resin, sodium hydroxide was relative strong, and sulfuric acid was relative weak.