高等学校化学学报
高等學校化學學報
고등학교화학학보
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
2010年
3期
571-576
,共6页
徐海丽%曹琪%王先友%陈权启%廖丽
徐海麗%曹琪%王先友%陳權啟%廖麗
서해려%조기%왕선우%진권계%료려
聚苯胺%聚中性红%共聚合%对甲基苯磺酸%乳液聚合%超级电容器
聚苯胺%聚中性紅%共聚閤%對甲基苯磺痠%乳液聚閤%超級電容器
취분알%취중성홍%공취합%대갑기분광산%유액취합%초급전용기
Polyaniline%Poly(neutral red)%Copolymerization%Paratoluenesulfonic acid%Emulsion polymerization%Supercapacitor
以对甲基苯磺酸(TSA)为掺杂剂和乳化剂,过硫酸铵(APS)为引发剂,采用现场乳液聚合方法合成了对甲基苯磺酸掺杂聚(苯胺/中性红)复合材料(TSA-PANI/PNR).利用X射线衍射(XRD)和电子扫描显微镜(SEM)对共聚物复合材料的结构和形貌进行了分析和表征.以此复合材料为活性物质制备电极,以l mol/L H_2SO_4水溶液为电解液组装超级电容器,通过恒电流充放电、循环伏安和交流阻抗等技术研究了其电化学性能.研究结果表明,TSA-PANI/PNR电极具有比TSA/PANI更优良的电化学性能.扫描速度为1 mV/s的循环伏安曲线计算结果表明,其单电极比电容可达到1350 F/g,而TSA/PANI在相同的扫速下其单电极比电容仅为1038 F/g;在5 mA放电电流下,TSA-PANI/PNR组装的电容器首次充放电比电容可达到348 F/g,1000次循环后容量保持87%.
以對甲基苯磺痠(TSA)為摻雜劑和乳化劑,過硫痠銨(APS)為引髮劑,採用現場乳液聚閤方法閤成瞭對甲基苯磺痠摻雜聚(苯胺/中性紅)複閤材料(TSA-PANI/PNR).利用X射線衍射(XRD)和電子掃描顯微鏡(SEM)對共聚物複閤材料的結構和形貌進行瞭分析和錶徵.以此複閤材料為活性物質製備電極,以l mol/L H_2SO_4水溶液為電解液組裝超級電容器,通過恆電流充放電、循環伏安和交流阻抗等技術研究瞭其電化學性能.研究結果錶明,TSA-PANI/PNR電極具有比TSA/PANI更優良的電化學性能.掃描速度為1 mV/s的循環伏安麯線計算結果錶明,其單電極比電容可達到1350 F/g,而TSA/PANI在相同的掃速下其單電極比電容僅為1038 F/g;在5 mA放電電流下,TSA-PANI/PNR組裝的電容器首次充放電比電容可達到348 F/g,1000次循環後容量保持87%.
이대갑기분광산(TSA)위참잡제화유화제,과류산안(APS)위인발제,채용현장유액취합방법합성료대갑기분광산참잡취(분알/중성홍)복합재료(TSA-PANI/PNR).이용X사선연사(XRD)화전자소묘현미경(SEM)대공취물복합재료적결구화형모진행료분석화표정.이차복합재료위활성물질제비전겁,이l mol/L H_2SO_4수용액위전해액조장초급전용기,통과항전류충방전、순배복안화교류조항등기술연구료기전화학성능.연구결과표명,TSA-PANI/PNR전겁구유비TSA/PANI경우량적전화학성능.소묘속도위1 mV/s적순배복안곡선계산결과표명,기단전겁비전용가체도1350 F/g,이TSA/PANI재상동적소속하기단전겁비전용부위1038 F/g;재5 mA방전전류하,TSA-PANI/PNR조장적전용기수차충방전비전용가체도348 F/g,1000차순배후용량보지87%.
Using paratoluenesulfonic acid(TSA) as dopant and emulsifier, and ammonium persulfate(APS) as initiator, the composites of polyaniline, TSA and neutral red(TSA-PANI/PNR) were synthesized by emulsion polymerization. The structure and morphology of the composites were investigated by X-ray diffraction(XRD) and scanning electron microscopy(SEM). Symmetric redox supercapacitor was assembled with TSA-PANI/PNR as active electrode material and an l mol/L H_2SO_4 aqueous solution as electrolyte. The electrochemical performances of the supercapacitors were characterized by galvanostatic charge-discharge, cyclic voltammetry and A.C. impedance spectroscopy. The results show that TSA-PANI/PNR composite exhibits outstanding electrochemical capacitor performance compared with TSA/PANI electrode. The specific capacitance measured from cyclic voltammetry is 1350 F/g for TSA-PANI/PNR composite material and 1038 F/g for TSA/PANI at 1 mV/s scan rate;the initial specific capacitance of the TSA-PANI/PNR supercapacitor is about 348 F/g at a constant current of 5 mA. Meanwhile, the retention of the capacitance after 1000 charge-discharge cycles was 87%.