吉首大学学报:自然科学版
吉首大學學報:自然科學版
길수대학학보:자연과학판
Journal of Jishou University(Natural Science Edition)
2011年
2期
83-88
,共6页
许友泽%成应向%向仁军%王强强%李小娇
許友澤%成應嚮%嚮仁軍%王彊彊%李小嬌
허우택%성응향%향인군%왕강강%리소교
重金属沉渣%土著微生物%浸出%余渣%环境活性
重金屬沉渣%土著微生物%浸齣%餘渣%環境活性
중금속침사%토저미생물%침출%여사%배경활성
heavy metal sediment%indigenous microorganisms%leaching%residues%environmental availability bility
在pH值为3.0、温度为30℃、矿浆质量分数为7%的优化浸出条件下,通过摇瓶试验,结合X射线衍射分析、BCR法3步连续提取,研究了土著微生物浸出重金属沉渣后余渣中重金属的潜在毒性。结果表明:土著微生物浸出7d后,沉渣中Cd,Mn,Cu,Pb,Zn含量分别由原来的4530,7650,830,29530,62350mg/kg降低至730,1280,390,13810,15650mg/kg.浸出过程沉渣中Cd,Mn,Cu,Pb,Zn等重金属的酸可提取态相对含量显著降低,残渣态相对含量提高.余渣环境活性和潜在危害低于《危险废物鉴别标准》(GB5085.3—2007)的规定,土著微生物浸出能有效实现重金属沉渣的资源化和无害化.
在pH值為3.0、溫度為30℃、礦漿質量分數為7%的優化浸齣條件下,通過搖瓶試驗,結閤X射線衍射分析、BCR法3步連續提取,研究瞭土著微生物浸齣重金屬沉渣後餘渣中重金屬的潛在毒性。結果錶明:土著微生物浸齣7d後,沉渣中Cd,Mn,Cu,Pb,Zn含量分彆由原來的4530,7650,830,29530,62350mg/kg降低至730,1280,390,13810,15650mg/kg.浸齣過程沉渣中Cd,Mn,Cu,Pb,Zn等重金屬的痠可提取態相對含量顯著降低,殘渣態相對含量提高.餘渣環境活性和潛在危害低于《危險廢物鑒彆標準》(GB5085.3—2007)的規定,土著微生物浸齣能有效實現重金屬沉渣的資源化和無害化.
재pH치위3.0、온도위30℃、광장질량분수위7%적우화침출조건하,통과요병시험,결합X사선연사분석、BCR법3보련속제취,연구료토저미생물침출중금속침사후여사중중금속적잠재독성。결과표명:토저미생물침출7d후,침사중Cd,Mn,Cu,Pb,Zn함량분별유원래적4530,7650,830,29530,62350mg/kg강저지730,1280,390,13810,15650mg/kg.침출과정침사중Cd,Mn,Cu,Pb,Zn등중금속적산가제취태상대함량현저강저,잔사태상대함량제고.여사배경활성화잠재위해저우《위험폐물감별표준》(GB5085.3—2007)적규정,토저미생물침출능유효실현중금속침사적자원화화무해화.
Shaking flask experiments were used to study the indigenous microorganisms leaching of heavy metals from sediment in the optimum conditions,which were determined to be pH = 3.0,65℃ and 7% pulp density. Residues from the bioleaching were analyzed through XRD and three-stage BCR sequential extraction procedure. Results show that heavy metal(Cd, Mn, Cu, Pb, Zn) contents sharply decrease over 7 days leaching,from 4 530 mg/kg,7 650 mg/kg,830 mg/kg,29 530 mg/kg,62 350 mg/kg to 730 mg/ kg, 1 280 mg/kg,390 mg/kg,13 810 mg/kg, 15 650 mg/kg respectively. Acid extractable percent content decreases remarkably during the bioleaching process;meanwhile,residual form percent content rises obvi- ously. The environmental availability and potential risk of heavy metals are less than the standards listed in Hazardous Waste Distinguishable Standard (GB 5085.3--2007). Indigenous microorganisms can effi- ciently implement the resources and harmlessness of heavy metals in sediment.