兰州大学学报(自然科学版)
蘭州大學學報(自然科學版)
란주대학학보(자연과학판)
JOURNAL OF LANZHOU UNIVERSITY
2005年
2期
46-49
,共4页
手性salen%镍(Ⅱ)二聚配合物%弱键作用
手性salen%鎳(Ⅱ)二聚配閤物%弱鍵作用
수성salen%얼(Ⅱ)이취배합물%약건작용
chiral salen%nickel ( Ⅱ ) dimer complex%weak bonding
合成和表征了一种新的salen镍配合物,并报道了其单晶衍射数据.化合物4:[NiC28H20Cl2N2O2]·CH2Cl2,M=631.00,单斜,P21/c,a=1.1086(2)nm,b=1.7521(4)nm,c=1.4819(3)nm,β=105.06(3)°,Z=4,V=2.779 5(10)nm3,Dc=1.508 g/cm3,R1=0.0531,R2=0.1136.
閤成和錶徵瞭一種新的salen鎳配閤物,併報道瞭其單晶衍射數據.化閤物4:[NiC28H20Cl2N2O2]·CH2Cl2,M=631.00,單斜,P21/c,a=1.1086(2)nm,b=1.7521(4)nm,c=1.4819(3)nm,β=105.06(3)°,Z=4,V=2.779 5(10)nm3,Dc=1.508 g/cm3,R1=0.0531,R2=0.1136.
합성화표정료일충신적salen얼배합물,병보도료기단정연사수거.화합물4:[NiC28H20Cl2N2O2]·CH2Cl2,M=631.00,단사,P21/c,a=1.1086(2)nm,b=1.7521(4)nm,c=1.4819(3)nm,β=105.06(3)°,Z=4,V=2.779 5(10)nm3,Dc=1.508 g/cm3,R1=0.0531,R2=0.1136.
A new salen nickel complex was synthesized and characterized along with the single crystal X-ray diffraction analysis. Compound 4: [NiC28H20Cl2N2O2]·CH2Cl2, M=631.00, Monoclinic,P21/c, a= 1.1086(2)nm, b=1.752 1(4)nm, c=1.4819(3)nm, β=105.06(3)°, Z=4, V=2.7795(10)nm3,Dc=1.508 g/cm3, R1=0.0531, R2=0.1136.
