CAJ | 학술논문

大环双核铜(Ⅱ)配合物由N,N'-二甲基-N,N'-二(3-甲酰基-5-氯水杨醛)乙二胺和1,3-丙二胺,与铜(Ⅱ)反应形成的,经过X-射线单晶衍射结果表明:d=0.871 05(16)nm,b=0.95778(18)nm,c=1.8104(3)nm,β=100.761(18)°,y=1.483 8(5)nm3,Z=2,Dc=1.762Mg·m-3,μ=1.85 mm-1,F(000)=796,and final R1=0.061,wR2=0.126.晶体结构表明:两个铜离子位于双核大环中间,与大环的胺、亚胺以及酚羟基的氧进行配位.磁性结果表明配合物为反铁磁性.
대배쌍핵동(Ⅱ)배합물유N,N'-이갑기-N,N'-이(3-갑선기-5-록수양철)을이알화1,3-병이알,여동(Ⅱ)반응형성적,경과X-사선단정연사결과표명:d=0.871 05(16)nm,b=0.95778(18)nm,c=1.8104(3)nm,β=100.761(18)°,y=1.483 8(5)nm3,Z=2,Dc=1.762Mg·m-3,μ=1.85 mm-1,F(000)=796,and final R1=0.061,wR2=0.126.정체결구표명:량개동리자위우쌍핵대배중간,여대배적알、아알이급분간기적양진행배위.자성결과표명배합물위반철자성.
The dinuclear copper(Ⅱ) macrocyclic complex has been synthesized by condensation between N,N'-dimethyl-N,N'-bis(3-formyl-5-chlorosalicylidene)ethylene diamine and 1,3-propanediamine in the presence of copper(Ⅱ). The complex was determined by X-ray diffractions single crystal structure analysis. The results indicates that the complex crystallizes in monoclinic, space group P21, Flack parameters(x) =0.06(2), with a=0.871 05(16) nm,F(000)=796, and final R1=0.061, wR2=0. 126, The crystal structure shows that the two copper(Ⅱ) ions in the phenolbased macrocyclic dinuclear complex, are coordinated with (Namine)2O2 and (Nimine)2O2 sites. Magnetic measurements reveal an antiferromagentic interaction in the complex. CCDC: 624712.