无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2004年
1期
53-56
,共4页
毛少瑜%李满荣%魏赞斌%宓锦校%赵景泰
毛少瑜%李滿榮%魏讚斌%宓錦校%趙景泰
모소유%리만영%위찬빈%복금교%조경태
交叠生长结构%硼磷酸盐%水热合成%铟
交疊生長結構%硼燐痠鹽%水熱閤成%銦
교첩생장결구%붕린산염%수열합성%인
intergrowth structure borophosphate hydrothermal synthesis indium
Several indium borophosphates have been reported recently, including KIn[BP2O8(OH)]( Ⅰ ) and NaIn[BP2O8(OH)]( Ⅱ ). The latter two compounds were synthesized under mild hydrothermal conditions, and have the samemolar ratio (MⅠ:In:B:P:O:H) in molecular formula but with different structure types. Compound Ⅰ crystallizes inthe triclinic system with space group P1 (No.2), a=0.52638(4) nm, b=0.84791(5) nm, c=0.81469(9) nm, α=91.1741 (7) °, β=93.061 (7) °, γ=79.823 (5) °, V=0.3573 nm3, Z=2; while compound Ⅱ possesses a monoclinicstructure with space group P21/n (No. 14) with a=0.5177(1) nm, b=1.6815(3) nm, c=0.7684(2) nm, β=94.10(3) °,V=0.6672(2) nm3, Z=4. Eight-membered-ring and six-membered-ring are formed by alternating borate, phosphatetetrahedra and In-coordination octahedron sharing corners via common oxygen atoms in compound Ⅰ and Ⅱrespectively. The polyhedra in the structure are oriented along certain direction to form alternating layeredfragments. These two structure types can be considered as intergrowth structures, which consist of the samelayered fragments growing in different orientations. Other structure intergrowth possibilities are also expected insimilar systems. CSD: Ⅰ, 409583; Ⅱ, 413343.