中国有色金属学报(英文版)
中國有色金屬學報(英文版)
중국유색금속학보(영문판)
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
2011年
4期
814-819
,共6页
何胜英%孙悦%陈民芳%刘德宝%叶新羽
何勝英%孫悅%陳民芳%劉德寶%葉新羽
하성영%손열%진민방%류덕보%협신우
β-磷酸钙%镁基复合材料%显微组织%力学性能%生物可降解
β-燐痠鈣%鎂基複閤材料%顯微組織%力學性能%生物可降解
β-린산개%미기복합재료%현미조직%역학성능%생물가강해
β-tricalcium phosphate%magnesium composite%microstructure%mechanical properties%biodegradation
镁合金具有优异的生物相容性,但在生理环境中过快的腐蚀降解速率制约其成为可降解植入材料.此外,镁合金的力学性能也较低.通过添加纳米β-TCP颗粒来改善Mg-Zn-Zr合金的显微组织及性能,制备挤压态的Mg-3Zn-0.8Zr合金和Mg-3Zn-0.8Zr/xβ-TCP(x=0.5,1.0,1.5)复合材料.添加纳β-TCP增强体的复合材料其晶粒明显细化.拉伸实验结果表明,添加fl-TCP后,复合材料的极限拉伸强度和伸长率均有所提高.电化学测试结果表明,复合材料在模拟体液中的抗蚀性较合金基体显著提高,其中Mg-3Zn0.8-Zr/1.0β-TCP复合材料的腐蚀电极电位为-1.547 V,其腐蚀电流密度为1.20×10-6A/cm2.
鎂閤金具有優異的生物相容性,但在生理環境中過快的腐蝕降解速率製約其成為可降解植入材料.此外,鎂閤金的力學性能也較低.通過添加納米β-TCP顆粒來改善Mg-Zn-Zr閤金的顯微組織及性能,製備擠壓態的Mg-3Zn-0.8Zr閤金和Mg-3Zn-0.8Zr/xβ-TCP(x=0.5,1.0,1.5)複閤材料.添加納β-TCP增彊體的複閤材料其晶粒明顯細化.拉伸實驗結果錶明,添加fl-TCP後,複閤材料的極限拉伸彊度和伸長率均有所提高.電化學測試結果錶明,複閤材料在模擬體液中的抗蝕性較閤金基體顯著提高,其中Mg-3Zn0.8-Zr/1.0β-TCP複閤材料的腐蝕電極電位為-1.547 V,其腐蝕電流密度為1.20×10-6A/cm2.
미합금구유우이적생물상용성,단재생리배경중과쾌적부식강해속솔제약기성위가강해식입재료.차외,미합금적역학성능야교저.통과첨가납미β-TCP과립래개선Mg-Zn-Zr합금적현미조직급성능,제비제압태적Mg-3Zn-0.8Zr합금화Mg-3Zn-0.8Zr/xβ-TCP(x=0.5,1.0,1.5)복합재료.첨가납β-TCP증강체적복합재료기정립명현세화.랍신실험결과표명,첨가fl-TCP후,복합재료적겁한랍신강도화신장솔균유소제고.전화학측시결과표명,복합재료재모의체액중적항식성교합금기체현저제고,기중Mg-3Zn0.8-Zr/1.0β-TCP복합재료적부식전겁전위위-1.547 V,기부식전류밀도위1.20×10-6A/cm2.
Magnesium alloys have good biocompatibility, but their mechanical properties and corrosion resistance may not be satisfied for using as degradable materials within bone due to its high corrosion rate in the physiological environment. Nano β-TCP particles were added into Mg-Zn-Zr alloy to improve its mierostructure and the properties. As-extruded Mg-3Zn-0.8Zr alloy and Mg-3Zn-O.8Zr/xβ-TCP (x=0.5%, 1.0% and 1.5%) composites were respectively fabricated. The grains of Mg-Zn-Zr/β-TCP composites were significantly refined. The results of the tensile tests indicate that the ultimate tensile strength and the elongation of composites were improved with the addition of β-TCP. The electrochemical test result in simulation body fluid shows that the corrosion resistance of the composites was strongly enhanced comparing with that of the alloy. The corrosion potential of Mg-3Zn0.8-Zr/1.0β-TCP composite is -1.547 V and its corrosion current density is 1.20×10-6 A/cm2.