中国科学D辑(英文版)
中國科學D輯(英文版)
중국과학D집(영문판)
SCIENCE IN CHINA（SCIENTIA SINICA）
2002年
11期
999-1007
,共9页
孙樯%谢鸿森%郑海飞%郭捷%丁东业
孫檣%謝鴻森%鄭海飛%郭捷%丁東業
손장%사홍삼%정해비%곽첩%정동업
water%albite glasses%solubility mechanism
On the basis of FTIR and Raman spectra studies on hydrous albite glasses, it is found that there exist two water solubility mechanisms in albite melts simultaneously. On the one hand, water interacts with Al -O°-Al to produce the Q3 Al-OH, leading to depolymerization, and this results in the appearance of 4500 cm(1 in FTIR spectra and 900 cm(1 in Raman spectra. On the other hand, the exchange of H+ in water with Na+ in albite melt as charge-balancing cation occurs at the same time. In the initial stage, the production of Al -OH is the dominant solubility mechanism, at the stage of higher water contents, the exchange of H+ with Na+ becomes the important dissolution mechanism. The dissolution of water into albite melt can be expressed as H2O+ 3NaAlSi3O8 = 2NaAl(OH)Si3O7.5 +HAlSi3O8 +NaOH.
