CAJ | 학술논문

以K3Mn(CN)6, N,N-二甲基甲酰胺和Eu(NO3)3*6H2O 为原料合成了新型一维链状氰根桥联配合物［Eu(DMF)4(H2O)2Mn(CN)6*H2O］n, 并通过元素分析、红外光谱和紫外光谱进行了表征. 利用单晶X射线四圆衍射测定了配合物的晶体结构, 结果表明，晶体属单斜晶系, P21/c空间群, 晶胞参数a=1.299 2(3) nm, b=1.276 4(3) nm, c=1.915 4(4) nm, β=109.42(3)°, V=2.995 6(12) nm3, Dx=1.573 Mg/m3, Z=4, R=0.037 2, Rw=0.096 2, GOF=1.095. 在Eu和Mn原子之间存在两个CN桥, 配合物呈现一维链状结构.
이K3Mn(CN)6, N,N-이갑기갑선알화Eu(NO3)3*6H2O 위원료합성료신형일유련상청근교련배합물［Eu(DMF)4(H2O)2Mn(CN)6*H2O］n, 병통과원소분석、홍외광보화자외광보진행료표정. 이용단정X사선사원연사측정료배합물적정체결구, 결과표명，정체속단사정계, P21/c공간군, 정포삼수a=1.299 2(3) nm, b=1.276 4(3) nm, c=1.915 4(4) nm, β=109.42(3)°, V=2.995 6(12) nm3, Dx=1.573 Mg/m3, Z=4, R=0.037 2, Rw=0.096 2, GOF=1.095. 재Eu화Mn원자지간존재량개CN교, 배합물정현일유련상결구.
Using K3Mn(CN)6, N,N-dimethylformamide(DMF) and Eu(NO3)3*6H2O as reactants, a novel one dimensional cyano-bridged chain complex ［Eu(DMF)4*(H2O)2Mn(CN)6*H2O］n has been first synthesized and characterized with elemental analysis, IR, UV spectra and X-ray crystal analysis. The complex crystallizes in the monoclinic P21/c space group, with lattice parameters a=1.299　2(3) nm, b=1.276　4(3) nm, c=1.915　4(4) nm, β=109.42(3)°, V=2.995　6(12) nm3, Dx=1.573 Mg/m3, Z=4, R=0.037　2, Rw=0.096　2, GOF=1.095. The complex shows one dimensional chain structure due to the two bridging CN between Eu and Mn atom.