清华大学学报(英文版)
清華大學學報(英文版)
청화대학학보(영문판)
TSINGHUA SCIENCE AND TECHNOLOGY
2002年
1期
73-77
,共5页
张志禹%胡中桥%杨基础%李以圭
張誌禹%鬍中橋%楊基礎%李以圭
장지우%호중교%양기출%리이규
Boublík-Alder-Chen-Kreglewshi (BACK)%statistical associating fluid theory (SAFT)%equation of state%supercritical fluids%vapor-liquid equilbrium
The statistical associating fluid theory (SAFT)-Boublík-Alder-Chen- Kreglewshi(BACK) equation of state is employed to correlate vapor-liquid equilibria of 16 binary mixtures composed of supercritical fluids with other fluids at elevated pressures. The van der Waals mixing rules are used and the binary parameters are adjusted to experimental data. The SAFT-BACK equation of state provides a better correlation of vapor-liquid equilibrium than the original BACK equation. Consequently, the binary parameters computed from the data sets can be used to accurately predict the saturated densities of the vapor and liquid phases.
