CAJ | 학술논문

本文考察了WO３： TiO２混合氧化物电致变色的机理及WO３：TiO２厚度不同的器件的电致变色特性。结果表明：WO３：TiO２混合氧化物电致变色的过程符合电化学氧化还原反应，在电场作用下，着色前后离子价态发生可逆变化，着色后膜层处于混合价态离子共存状态。适当的TiO２掺杂量可以改善WO３：TiO２电致变色器件的变色特性、响应时间和器件寿命。
본문고찰료WO３： TiO２혼합양화물전치변색적궤리급WO３：TiO２후도불동적기건적전치변색특성。결과표명：WO３：TiO２혼합양화물전치변색적과정부합전화학양화환원반응，재전장작용하，착색전후리자개태발생가역변화，착색후막층처우혼합개태리자공존상태。괄당적TiO２참잡량가이개선WO３：TiO２전치변색기건적변색특성、향응시간화기건수명。
The electrochromic mechanism of mix-o xide and properties of the device with different thickness of WO３：TiO 2 are investigated in this paper.The results show that the electrochromic proce ss of WO３：TiO２ conforms to response of oxido-reduction in electroch e mistry;the valence state of ion is changed in reversibility by electric field;th e ions of mix valence state are coexistence after coloring;the properties、respo nse time and lifetime of electrochromic device of WO３：TiO２ are mende d with appropriate TiO２．